CaCl2 CsCl CuCl CuCl2 KCl LiCl NaCl NH4Cl PtCl4 Basic
PVC -(C2Cl)- 2-Chloro-styrene

XPS Spectra
Chlorine (Cl) Compounds
The XPS Spectra section provides raw and processed survey spectra, chemical state spectra, BE values, FWHM values, and overlays of key spectra.
Atom% values from surveys are based on sample, as received, and Scofield cross-sections. Atom% values are corrected for IMFP and PE.
Peak-fits are guides for practical, real-world applications. Peak-fits are not fully optimized or designed to test any theory.

Platinum Tetra-chloride  (PtCl4 – degrades with time)
Survey, Peak-fits, BEs, FWHMs, and Peak Labels

→  Periodic Table   → Six (6) BE Tables
Survey Spectrum from PtCl4
Freshly exposed bulk, Flood gun is OFF, sample is conductive, Ag (3d5/2) FWHM = 1.3 eV
→  Periodic Table  → Six (6) BE Tables
Pt (4f) Spectrum from PtCl4 – Raw
Fresh exposed bulk, conductive, Flood gun OFF, C (1s) BE = 284.5 eV, Ag FWHM = 0.75 eV		 Pt (4f) Spectrum from PtCl4 – Peak-Fit
Freshly exposed bulk, conductive, Flood gun OFF, C (1s) BE = 284.5 eV, Ag FWHM = 0.75 eV
 
Pt (4f) Spectrum from PtCl4 – Extended Range
Fresh exposed bulk, conductive, Flood gun OFF, C (1s) BE = 284.5 eV, Ag FWHM = 0.75 eV		 Pt (4f) Spectrum from PtCl4 – Raw – Vertically Expanded
Freshly exposed bulk, conductive, Flood gun OFF, C (1s) BE = 284.5 eV, Ag FWHM = 0.75 eV

→  Periodic Table  → Six (6) BE Tables
Cl (2p) Spectrum from PtCl4 – Raw
Freshly exposed bulk, conductive, Flood gun OFF, C (1s) BE = 284.5 eV, Ag FWHM = 0.75 eV		 Cl (2p) Spectrum from PtCl4 – Peak-Fit
Freshly exposed bulk, conductive, Flood gun OFF, C (1s) BE = 284.5 eV, Ag FWHM = 0.75 eV
→  Periodic Table  → Six (6) BE Tables
Cl (2p) Spectrum from PtCl4 – Raw – Extended Range
Freshly exposed bulk, conductive, Flood gun OFF, C (1s) BE = 284.5 eV, Ag FWHM = 0.75 eV		 Cl (2p) Spectrum from PtCl4 – Raw – Vertically Expanded
Freshly exposed bulk, conductive, Flood gun OFF, C (1s) BE = 284.5 eV, Ag FWHM = 0.75 eV
→  Periodic Table  → Six (6) BE Tables
C (1s) Spectrum from PtCl4 – Raw
Freshly exposed bulk, conductive, Flood gun OFF, C (1s) BE = 284.5 eV, Ag FWHM = 0.75 eV		 C (1s) Spectrum from PtCl4 – Peak-Fit
Freshly exposed bulk, conductive, Flood gun OFF, C (1s) BE = 284.5 eV, Ag FWHM = 0.75 eV
→  Periodic Table  → Six (6) BE Tables
Cl (2s) Spectrum from PtCl4 – Raw
Freshly exposed bulk, conductive, Flood gun OFF, C (1s) BE = 284.5 eV, Ag FWHM = 0.75 eV		 Cl (2s) Spectrum from PtCl4 – Peak-Fit
Freshly exposed bulk, conductive, Flood gun OFF, C (1s) BE = 284.5 eV, Ag FWHM = 0.75 eV

 
→  Periodic Table  → Six (6) BE Tables
Pt (4f) Spectrum from PtCl4 – degrades with time
Freshly exposed bulk, conductive, Flood gun OFF, C (1s) BE = 284.5 eV, Ag FWHM = 0.75 eV		 Pt (4f) Spectrum from PtCl4 – Peak-Fit – end of analysis
Freshly exposed bulk, conductive, Flood gun OFF, C (1s) BE = 284.5 eV, Ag FWHM = 0.75 eV
→  Periodic Table  → Six (6) BE Tables
O (KLL) Auger Signals from PtCl4 – Raw
Freshly exposed bulk, conductive, Flood gun OFF, C (1s) BE = 284.5 eV, Ag FWHM = 0.75 eV		 Valence Band Signals from PtCl4 – Raw
Freshly exposed bulk, conductive, Flood gun OFF, C (1s) BE = 284.5 eV, Ag FWHM = 0.75 eV
na
 
Overlays
→  Periodic Table  → Six (6) BE Tables
Valence Band Spectra – Overlay of Pto and PtCl4
Freshly exposed bulk, conductive, Flood gun OFF, C (1s) BE = 284.5 eV, Ag FWHM = 0.75 eV		 Pt (4f) Spectra – Overlay of Pto and PtCl4
Freshly exposed bulk, conductive, Flood gun OFF, C (1s) BE = 284.5 eV, Ag FWHM = 0.75 eV

End-of-spectra

Price to purchase raw data sets:
Raw spectra – VAMAS ASCII format ($6)
Raw spectra – SDP binary format ($5)
SDP v9 – $145 (3 yr license)

 

 

Transmission Function Tests
 

December 2015 – Transmission Function of Thermo K-Alpha Plus
→  Periodic Table 
Survey Spectra of Ion Etched Copper (Cu), PEs = 50, 100, 150 and 200 eV
→  Periodic Table 
March 2016 – Transmission Function of Thermo K-Alpha Plus 
 
Survey Spectra of Ion Etched Copper (Cu), PEs = 100, 150 and 200 eV
→  Periodic Table  
August 2019 – Transmission Function of Thermo K-Alpha Plus
 
Survey Spectra of HOPG (C), PEs = 20, 50, 100 and 200 eV
→  Periodic Table  
January 2022 – Transmission Function of Thermo K-Alpha Plus
Survey Spectra of Ion Etched Copper (Cu), PEs = 100, 120, 140, 160, 180 and 200 eV

End-of-Transmission-Function-Tests

 

Six (6) Chemical State Tables of Cl (2p3/2) BEs

 

  • The XPS Library Spectra-Base
  • PHI Handbook
  • Thermo-Scientific Website
  • XPSfitting Website
  • Techdb Website
  • NIST Website

 

 

Notes of Caution when using Published BEs and BE Tables from Insulators and Conductors:

  • Accuracy of Published BEs
    • The accuracy depends on the calibration BEs used to calibrate the energy scale of the instrument.  Cu (2p3/2) BE can vary from 932.2 to 932.8 eV for old publications
    • Different authors use different BEs for the C (1s) BE of the hydrocarbons found in adventitious carbon that appears on all materials and samples.  From 284.2 to 285.3 eV
    • The accuracy depends on when the authors last checked or adjusted their energy scale to produce the expected calibration BEs
  • Worldwide Differences in Energy Scale calibrations
    • For various reasons authors still use older energy scale calibrations
    • Some authors still adjust their energy scale so Cu (2p3/2) appears at 932.2 eV or 932.8 eV because this is what the maker taught them
    • This range causes BEs in the higher BE end to be larger than expected
    • This variation increases significantly above 600 eV BE
  • Charge Compensation
    • Samples that behave as true insulators normally require the use of a charge neutralizer (electron flood gun with or without Ar+ ions) so that the measured chemical state spectra can be produced without peak-shape distortions or sloping tails on the low BE side of the peak envelop.
    • Floating all samples (conductive, semi-conductive, and non-conductive) and always using the electron flood gun is considered to produce more reliable BEs and is recommended.
  • Charge Referencing Methods for Insulators
    • Charge referencing is a common method, but it can produce results that are less reliable.
    • When an electron flood gun is used, the BE scale will usually shift to lower BE values by 0.01 to 5.0 eV depending on your voltage setting. Normally, to correct for this flood gun induced shift, the BE of the hydrocarbon C (1s) peak maximum from adventitious carbon is used to correct for the charge induced shift.
    • The hydrocarbon peak is normally the largest peak at the lowest BE.
    • Depending on your preference or training, the C (1s) BE assigned to this hydrocarbon peak varies from 284.8 to 285.0 eV.  Other BEs can be as low as 284.2 eV or as high as 285.3 eV
    • Native oxides that still show the pure metal can suffer differential charging that causes the C (1s) and the O (1s) and the Metal Oxide BE to be larger
    • When using the electron flood gun, the instrument operator should adjust the voltage and the XY position of the electron flood gun to produce peaks from a strong XPS signal (eg O (1s) or C (1s) having the most narrow FWHM and the lowest experimentally measured BE.

→  Periodic Table 

Table #1

Cl (2p3/2) Chemical State BEs from:  “The XPS Library Spectra-Base”

C (1s) BE = 285.0 eV for TXL BEs
and C (1s) BE = 284.8 eV for NIST BEs

Element Atomic # Compound As-Measured by TXL or
NIST Average BE		 Largest BE Hydrocarbon C (1s) BE  Source
Cl 17 Cl-NH4 198.1 eV 285.0 eV The XPS Library
Cl 17 Cl-K 198.5 eV 285.0 eV The XPS Library
Cl 17 Cu-Cl2 198.9 eV 284.8 eV Avg BE – NIST
Cl 17 Cl-Li 199.0 eV 285.0 eV The XPS Library
Cl 17 Cl-Na 199.3 eV 285.0 eV The XPS Library
Cl 17 Pt-Cl2 199.6 eV 285.0 eV The XPS Library
Cl 17 Cl-C polymer 200.4 eV 200.8 eV 285.0 eV The XPS Library
Cl 17 KClO3 (N*3) 205.9 eV 206.7 eV 284.8 eV Avg BE – NIST
Cl 17 KClO4 (N*2) 208.3 eV 208.7 eV 284.8 eV Avg BE – NIST

 

Charge Referencing

  • (N*number) identifies the number of NIST BEs that were averaged to produce the BE in the middle column.
  • Binding Energy Scale calibration expects Cu (2p3/2) BE = 932.62 eV and Au (4f7/2) BE = 83.98 eV.  BE (eV) Uncertainty Range:  +/- 0.2 eV
  • Charge Referencing of insulators is defined such that the Adventitious Hydrocarbon C (1s) BE (eV) = 285.0 eV.  NIST uses C (1s) BE = 284.8 eV 
  • Note:   Ion etching removes adventitious carbon, implants Ar (+), changes conductivity of surface, and degrades chemistry of various chemical states.
  • Note:  Ion Etching changes BE of C (1s) hydrocarbon peak.
  • TXL – abbreviation for: “The XPS Library” (https://xpsLibrary.com).  NIST:  National Institute for Science and Technology (in USA)

→  Periodic Table 

Table #2

Cl (2p3/2) Chemical State BEs from:  “PHI Handbook”

C (1s) BE = 284.8 eV

 

→  Periodic Table 

Copyright ©:  Ulvac-PHI

Table #3

Cl (2p3/2) Chemical State BEs from:  “Thermo-Scientific” Website

C (1s) BE = 284.8 eV

Chemical state Binding energy, Cl (2p3/2) / eV
Organic Cl 200
Metal 198.5-200

→  Periodic Table 

Copyright ©:  Thermo Scientific 

Table #4

Cl (2p3/2) Chemical State BEs from:  “XPSfitting” Website

Chemical State BE Table derived by Averaging BEs in the NIST XPS database of BEs
C (1s) BE = 284.8 eV

 

→  Periodic Table 

Copyright ©:  Mark Beisinger

Table #5

Cl (2p3/2) Chemical State BEs from:  “Techdb.podzone.net” Website

 

XPS Spectra – Chemical Shift | Binding Energy
C (1s) BE = 284.6 eV

XPS(X線光電子分光法)スペクトル 化学状態 化学シフト ケミカルシフト

Element Level Compound B.E.(eV) min max
Cl 2p3/2 K2IrCl6 198.4 ±0.4 198.0 ～ 198.8
Cl 2p3/2 Pt(NH3)2Cl2 198.5 ±0.4 198.1 ～ 198.9
Cl 2p3/2 PdCl2 198.6 ±0.4 198.2 ～ 198.9
Cl 2p3/2 Alkali Chloride 198.7 ±0.6 198.1 ～ 199.2
Cl 2p3/2 NiCl2 199.4 ±0.4 199.0 ～ 199.7
Cl 2p3/2 CuCl2 199.7 ±0.4 199.3 ～ 200.0
Cl 2p3/2 p(CH2=CHCl) 200.0 ±0.3 199.7 ～ 200.3
Cl 2p3/2 C6H5Cl 200.5 ±0.5 200.0 ～ 201.0
Cl 2p3/2 KClO3 206.7 ±0.4 206.3 ～ 207.0
Cl 2p3/2 NaClO4 208.5 ±0.3 208.2 ～ 208.8
Cl 2p3/2 Perchlorate 208.7 ±0.5 208.2 ～ 209.2

 

→  Periodic Table 

 


Histograms of NIST BEs for Cl (2p3/2) BEs

Important Note:  NIST Database defines Adventitious Hydrocarbon C (1s) BE = 284.8 eV for all insulators.

Histogram indicates:  196.4 eV for Cl- in NaCl based on 8 literature BEs Histogram indicates:  195.0 eV for Cl- in KCl based on 7 literature BEs

Table #6


NIST Database of Cl (2p3/2) Binding Energies

NIST Standard Reference Database 20, Version 4.1

Data compiled and evaluated
by
Alexander V. Naumkin, Anna Kraut-Vass, Stephen W. Gaarenstroom, and Cedric J. Powell
©2012 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved.

Important Note:  NIST Database defines Adventitious Hydrocarbon C (1s) BE = 284.8 eV for all insulators.

 

Element Spectral Line Formula Energy (eV) Reference
Cl 2p3/2 [Tc((C6H5)2PCH2CH2P(C6H5)2)2Cl2]Cl 196.20  Click
Cl 2p3/2 [P(C6H5)4]Cl 196.40  Click
Cl 2p3/2 [P(C6H5)4]Cl 196.40  Click
Cl 2p3/2 [(CH3)4N]Cl 196.50  Click
Cl 2p3/2 [TeCl(CH2P(C6H5)3)3]Cl3 196.60  Click
Cl 2p3/2 [Te(CH2P(C6H5)3)4]Cl4 196.60  Click
Cl 2p3/2 [((C6H5)3P=CH2)3TeCl]Cl3 196.60  Click
Cl 2p3/2 [((C6H5)3P=CH2)4Te]Cl4 196.60  Click
Cl 2p3/2 [Tc((CH3)2PCH2CH2P(CH3)2)2Cl2]Cl 196.60  Click
Cl 2p3/2 (-CH2CH(C6H4CH2N(CH3)3(Cl))-)n 196.65  Click
Cl 2p3/2 [TeCl2(CH2P(C6H5)3)2]Cl2 196.70  Click
Cl 2p3/2 [((C6H5)3P=CH2)2TeCl2]Cl2 196.70  Click
Cl 2p3/2 [Ru2Cl3(P(C2H5)2-C6H5)6]Cl 196.80  Click
Cl 2p3/2 (-C6H4NHClC6H4NHC6H4NHClC6H4NH-)n 196.90  Click
Cl 2p3/2 [(Pt(P(C6H5)3)2S)2PtCl2] 197.00  Click
Cl 2p3/2 (-(CH(C(O)NH2)CH2)k-(CH(C(O)NH(CH2)3N(CH3)3Cl)CH2)m-)n 197.20  Click
Cl 2p3/2 [MoCl(CO)2(C3H5)(NC5H4C5H4N)] 197.30  Click
Cl 2p3/2 [ReCl(N2)((C6H5)2PCH2CH2P(C6H5)2)2] 197.30  Click
Cl 2p3/2 [Co2Cl2(CH3C(NOH)C(CH3)NCH2CH2NHCH2CH2NHCH2CH2NC(CH3)C(NOH)CH3)]Cl2 197.30  Click
Cl 2p3/2 [AuCl(CH2P(C6H5)3)2] 197.30  Click
Cl 2p3/2 [(C6H5)3PCH2]2AuCl 197.30  Click
Cl 2p3/2 [WCl(CO)2(C3H5)(NC5H4C5H4N)] 197.40  Click
Cl 2p3/2 [Mo2Cl4(C4H4N2)2] 197.50  Click
Cl 2p3/2 [WCl(CO)2(CH3C3H4)(C5H4N)2] 197.50  Click
Cl 2p3/2 [CoCl2(CH3C(NOH)C(CH3)NCH2CH2NC(CH3)C(NOH)CH3)] 197.50  Click
Cl 2p3/2 [(C6H5)3PCH2]-[(C6H5)3P]AuCl 197.50  Click
Cl 2p3/2 HCl/O2/Pb 197.50  Click
Cl 2p3/2 [Tl2Cl6((C2H5)2PC6H5)5] 197.60  Click
Cl 2p3/2 [(N(C2H5)4)W(CO)5]Cl 197.60  Click
Cl 2p3/2 [Pd2(SO2)Cl2((C6H5)2PCH2P(C6H5)2)2] 197.60  Click
Cl 2p3/2 [N(C2H5)4][Cr(CO)5Cl] 197.60  Click
Cl 2p3/2 [TeCl(CH2P(C6H5)3)3]Cl3 197.60  Click
Cl 2p3/2 [(C6H5)3PCH2]2CuCl 197.60  Click
Cl 2p3/2 [((C6H5)3P=CH2)3TeCl]Cl3 197.60  Click
Cl 2p3/2 TcCl[(C4H7N2O)2(C4H6N2O)(C4H9BO3)] 197.60  Click
Cl 2p3/2 TcCl[(C6H9N2O)2(C6H8N2O)(CH3BO3)] 197.60  Click
Cl 2p3/2 W2(mu-H)(mu-Cl)Cl4(C5H5N)4 197.60  Click
Cl 2p3/2 [(C6H5)3P]2AuCl 197.60  Click
Cl 2p3/2 RuCl3 197.60  Click
Cl 2p3/2 [Pt2(P(C6H5)3)4SSCH2Cl]Cl 197.60  Click
Cl 2p3/2 UCl4 197.70  Click
Cl 2p3/2 UCl5 197.70  Click
Cl 2p3/2 AgCl 197.70  Click
Cl 2p3/2 [N(C4H9)4]3[Mo2Cl9] 197.70  Click
Cl 2p3/2 [Mo6Cl8Cl4(SO(CH3)2)2] 197.70  Click
Cl 2p3/2 [MoCl(CO)2((C6H5)2PCH2CH2P(C6H5)2)(C3H5)] 197.70  Click
Cl 2p3/2 [RuCl3(NO2C6H4NN)(P(C6H5)3)2] 197.70  Click
Cl 2p3/2 [RuCl3(P(C6H5)3)2(CH3C6H4NN)] 197.70  Click
Cl 2p3/2 [RuCl3(CH3C6H4NNH)(P(C6H5)3)2] 197.70  Click
Cl 2p3/2 (-CH2CH(CH2NH3Cl)-)n 197.70  Click
Cl 2p3/2 [Mo(CO)5Clr(P(C6H5)4)] 197.70  Click
Cl 2p3/2 [AuCl((CH3)2S(O)CH2)2] 197.70  Click
Cl 2p3/2 KCl 197.80  Click
Cl 2p3/2 [Os(O2)(NH3)4]Cl2 197.80  Click
Cl 2p3/2 [Os(CO)Cl(P(C6H5)3)2(C5H3NOCH3)] 197.80  Click
Cl 2p3/2 [RhCl(P(C6H5)3)3] 197.80  Click
Cl 2p3/2 [Cr(CO)5Cl(P(C6H5)4)] 197.80  Click
Cl 2p3/2 [As(CH3-C6H4)3]2ClRuCl3RuCl[As(CH3-C6H4)3]2 197.80  Click
Cl 2p3/2 W2(mu-H)(mu-Cl)Cl4(C2H5C5H5N)4 197.80  Click
Cl 2p3/2 [C8H14C5H3]2TiCl2 197.88  Click
Cl 2p3/2 Cs2[Rh2Cl2(HCOO)4] 197.90  Click
Cl 2p3/2 [PtHCl(P(C6H5)3)2] 197.90  Click
Cl 2p3/2 [RhCl3(CH3CN)(P(C6H5)3)2] 197.90  Click
Cl 2p3/2 CsCl 197.90  Click
Cl 2p3/2 [WCl(CO)2((C6H5)2PCH2CH2P(C6H5)2)(C3H5)] 197.90  Click
Cl 2p3/2 [RhCl2(NO)(P(C6H5)3)2] 197.90  Click
Cl 2p3/2 [RuCl3(NO)((C6H5)3P)2] 197.90  Click
Cl 2p3/2 [RhCl(O)(P(C6H5)3)2] 197.90  Click
Cl 2p3/2 [RuCl3(ClC6H4NN)(P(C6H5)3)2] 197.90  Click
Cl 2p3/2 [RhCl2(C6H5CO)(P(C6H5)3)2] 197.90  Click
Cl 2p3/2 [RhCl2(CH3OC6H4NN)(P(C6H5)3)2] 197.90  Click
Cl 2p3/2 [IrCl3(CH3C6H4NNH)(P(C6H5)3)2] 197.90  Click
Cl 2p3/2 [PdCl2((C6H5)2AsCH2As(C6H5)2)2] 197.90  Click
Cl 2p3/2 [Pd2Cl2((C6H5)2PCH2P(C6H5)2)2] 197.90  Click
Cl 2p3/2 [RhCl2(CO)((C6H5)3P)2(CH3(CH2)14(C6H4))] 197.90  Click
Cl 2p3/2 [Mo4Cl4Cl4(P(C2H5)3)4] 197.90  Click
Cl 2p3/2 [C5H5(CH3)5)]2TiCl2 197.96  Click
Cl 2p3/2 [RhCl(C6H5NCO)2(P(C6H5)3)2] 198.00  Click
Cl 2p3/2 [RhCl(CS2)(P(C6H5)3)3] 198.00  Click
Cl 2p3/2 C(NH2)3Cl 198.00  Click
Cl 2p3/2 [RhCl2(CHCH2)(P(C6H5)3)3] 198.00  Click
Cl 2p3/2 KCl 198.00  Click
Cl 2p3/2 [PdCl2(C5H5N)2] 198.00  Click
Cl 2p3/2 [RhCl3(C5NH5)3] 198.00  Click
Cl 2p3/2 [RhCl3(C5NH5)3] 198.00  Click
Cl 2p3/2 [Mo6Cl8Cl4(P(C6H5)3)2] 198.00  Click
Cl 2p3/2 [PdCl2((C6H5)3P)2] 198.00  Click
Cl 2p3/2 [PtCl2(P(C6H5)3)2] 198.00  Click
Cl 2p3/2 [Rh(CO)Cl(P(C6H5)3)2] 198.00  Click
Cl 2p3/2 [PtClH(P(C2H5)3)2] 198.00  Click
Cl 2p3/2 [ReCl2(N)((CH3)2P(C6H5))3] 198.00  Click
Cl 2p3/2 [RhCl2(NO2C6H4NN)(P(C6H5)3)2] 198.00  Click
Cl 2p3/2 [RhCl2(C6H5)(P(C6H5)3)2] 198.00  Click
Cl 2p3/2 [RuCl(CH3C6H4NN)2(P(C6H5)3)2].BF4 198.00  Click
Cl 2p3/2 [RhCl2(CH3C6H4NN)(P(C6H5)3)2] 198.00  Click
Cl 2p3/2 [ReCl(CO)((CH3)2P(C6H5))4] 198.00  Click
Cl 2p3/2 [Pd2SCl2((C6H5)2PCH2P(C6H5)2)2] 198.00  Click
Cl 2p3/2 [RhCl(P(C6H5)3)3] 198.00  Click
Cl 2p3/2 [ReCl(CO)((C6H5)2PCH2CH2P(C6H5)2)2] 198.00  Click
Cl 2p3/2 [RhCl2((C6H5)3P)2(CH3(CH2)14)] 198.00  Click
Cl 2p3/2 RuCl2(P(C6H5)3)3 198.00  Click
Cl 2p3/2 [(Pt2(P(C6H5)3)4S2Pd)2Cl2][PF6]2 198.00  Click
Cl 2p3/2 [C9H16C5H3]2TiCl2 198.01  Click
Cl 2p3/2 [C5H8C5H3][C5H5]TiCl2 198.01  Click
Cl 2p3/2 [C7H12C5H3][C5H5]TiCl2 198.04  Click
Cl 2p3/2 [C7H12C5H3][C10H55]TiCl2 198.07  Click
Cl 2p3/2 [PtCl2(P(C2H5)3)2] 198.10  Click
Cl 2p3/2 [RhCl(C2H4)]2 198.10  Click
Cl 2p3/2 [RhCl(C2H4)]2 198.10  Click
Cl 2p3/2 [TlCl3(C5H5N)2] 198.10  Click
Cl 2p3/2 UCl3 198.10  Click
Cl 2p3/2 RbCl 198.10  Click
Cl 2p3/2 [Mo4Cl4Cl4(P(C4H9)3)4] 198.10  Click
Cl 2p3/2 Pd(NH3)4Cl2 198.10  Click
Cl 2p3/2 [Rh(NH3)6]Cl3 198.10  Click
Cl 2p3/2 [Zr(OH)2(CH3CH(NH2)COO)2]Cl2.3H2O 198.10  Click
Cl 2p3/2 [RhAs(C6H5)4]Cl4.CH3CN 198.10  Click
Cl 2p3/2 [PtCl6(-NHC(CH3)C(OH)C(CH2OH)C(CH2OH)CH-)2] 198.10  Click
Cl 2p3/2 [RuCl(NO)2(P(C6H5)3)2].BF4 198.10  Click
Cl 2p3/2 [N(C4H9)4]2[Mo5Cl13] 198.10  Click
Cl 2p3/2 [TeCl2(CH2P(C6H5)3)2]Cl2 198.10  Click
Cl 2p3/2 [RhCl(C8H12)(-CH2C-H(C6H4)PH2)] 198.10  Click
Cl 2p3/2 [((C6H5)3P=CH2)2TeCl2]Cl2 198.10  Click
Cl 2p3/2 Cl2/GaAs0.96 198.10  Click
Cl 2p3/2 [C5H8C5H3]2TiCl2 198.11  Click
Cl 2p3/2 [C8H14C5H3][C5H5]TiCl2 198.12  Click
Cl 2p3/2 [C5H8C5H3][C5H5]TiCl2 198.15  Click
Cl 2p3/2 [C9H16C5H3][C5H5]TiCl2 198.15  Click
Cl 2p3/2 [Mo2Cl4((C5H5N)NHCH3)2] 198.20  Click
Cl 2p3/2 [Mo2Cl4(P(C2H5)3)4] 198.20  Click
Cl 2p3/2 [RhCl3(S(C2H5)2)3] 198.20  Click
Cl 2p3/2 [RhCl3(S(C2H5)2)3] 198.20  Click
Cl 2p3/2 [VCl(C5H5)2] 198.20  Click
Cl 2p3/2 TiCl4 198.20  Click
Cl 2p3/2 TiCl4 198.20  Click
Cl 2p3/2 CsCl 198.20  Click
Cl 2p3/2 [Mo6Cl8Cl4(C5H5N)2] 198.20  Click
Cl 2p3/2 [PdCl2(C5H5N)2] 198.20  Click
Cl 2p3/2 [PdCl2((CH3)C3HNO(C6H5))2] 198.20  Click
Cl 2p3/2 [Rh(As(C6H5)4)]Cl4.2H2O 198.20  Click
Cl 2p3/2 [RhCl2(CO)(C6H5)(P(C6H5)3)2] 198.20  Click
Cl 2p3/2 [ReCl2(P(CH3)2(C6H5))4] 198.20  Click
Cl 2p3/2 [RhCl2(CO)((C6H5)3P)2(CH3(CH2)14)] 198.20  Click
Cl 2p3/2 (NH4)2[PtCl4] 198.20  Click
Cl 2p3/2 [N(C2H5)4][Mo(CO)5Cl] 198.20  Click
Cl 2p3/2 [RhCl(C8H12)(-CH2C-H(C6H4)PH2)] 198.20  Click
Cl 2p3/2 [(CH3)4N]2TcCl6 198.20  Click
Cl 2p3/2 W2(mu-H)(mu-Cl)Cl4(C5H5N)4 198.20  Click
Cl 2p3/2 [C5H8C5H3][C10H15]TiCl2 198.21  Click
Cl 2p3/2 [C5H5(CH3)5)C5H5]2TiCl2 198.22  Click
Cl 2p3/2 [C7H12C5H3][C5H5]TiCl2 198.22  Click
Cl 2p3/2 [C5H8C5H3][C10H15]TiCl2 198.27  Click
Cl 2p3/2 [C7H12C5H3]2TiCl2 198.28  Click
Cl 2p3/2 [C5H5(CH3)2)C5H5]TiCl2 198.28  Click
Cl 2p3/2 [(C5H5)2]TiCl2 198.29  Click
Cl 2p3/2 [PtCl2(P(C2H5)3)2] 198.30  Click
Cl 2p3/2 [Cu(H2NC(O)NHC(O)NH2)2]Cl2 198.30  Click
Cl 2p3/2 [Mn(H2NC(O)NHC(O)NH2)2]Cl2 198.30  Click
Cl 2p3/2 [NiCl(CFCF2)(P(C2H5)3)2] 198.30  Click
Cl 2p3/2 [NiCl(C6H5)(P(C2H5)3)2] 198.30  Click
Cl 2p3/2 NiCl2 198.30  Click
Cl 2p3/2 [TiCl2(C5H5)2] 198.30  Click
Cl 2p3/2 [PdCl2(CH3(C3HNO)CH3)2] 198.30  Click
Cl 2p3/2 [PtCl2((CH3)C3HNO(C6H5))2] 198.30  Click
Cl 2p3/2 [Re2Cl8(ClP(C2H5)3)2] 198.30  Click
Cl 2p3/2 [Re2Br4Cl4(ClP(C2H5)3)2] 198.30  Click
Cl 2p3/2 [OsCl2(P(C6H5)3)2(C5H4NO)] 198.30  Click
Cl 2p3/2 [OsCl2(P(C6H5)3)2(C5H3NOCH3)] 198.30  Click
Cl 2p3/2 NaCl 198.30  Click
Cl 2p3/2 UCl2O 198.30  Click
Cl 2p3/2 Cl in (-H(C6H4)PH2)n 198.30  Click
Cl 2p3/2 (P(C2H5)2-C6H5)2ClRuCl3Ru(P(C2H5)2-C6H5)3 198.30  Click
Cl 2p3/2 [P(C6H5)2(C7H7)]3RuCl3RuCl2[P(C6H5)2(C7H7)] 198.30  Click
Cl 2p3/2 ZrCl4 198.30  Click
Cl 2p3/2 [C5H5(CH3)2)]2TiCl2 198.35  Click
Cl 2p3/2 [Rh2Cl2(P(C6H5)3)4] 198.40  Click
Cl 2p3/2 [RhCl(C2H4)(P(C6H5)3)2] 198.40  Click
Cl 2p3/2 HCl.nH2O 198.40  Click
Cl 2p3/2 [Mo2Cl4(CH3P(C6H5)2)4] 198.40  Click
Cl 2p3/2 K3[RhCl6] 198.40  Click
Cl 2p3/2 K3[RhCl6] 198.40  Click
Cl 2p3/2 AuCl 198.40  Click
Cl 2p3/2 CuCl 198.40  Click
Cl 2p3/2 CuCl 198.40  Click
Cl 2p3/2 InCl 198.40  Click
Cl 2p3/2 KCl 198.40  Click
Cl 2p3/2 [NiCl2((C2H5)3P)2] 198.40  Click
Cl 2p3/2 [OsCl2(P(C6H5)3)2(C5H4NCOO)] 198.40  Click
Cl 2p3/2 [RhCl(C8H12)(-CH2C-H(C6H4)PH2)] 198.40  Click
Cl 2p3/2 [Tc((CH3)2PCH2CH2P(CH3)2)2Cl2]Cl 198.40  Click
Cl 2p3/2 RuCl3(P(CH3)2C6H5)3 198.40  Click
Cl 2p3/2 AgCl 198.40  Click
Cl 2p3/2 BaCl2 198.40  Click
Cl 2p3/2 TiCl4/W 198.40  Click
Cl 2p3/2 TiCl4/W 198.40  Click
Cl 2p3/2 PdCl2 198.50  Click
Cl 2p3/2 [Rh(NH3)6]Cl3 198.50  Click
Cl 2p3/2 [Hf(OH)2(CH3CH(NH2)COO)2]Cl2.3H2O 198.50  Click
Cl 2p3/2 [PtCl2(C3HNO(C6H5)2)2] 198.50  Click
Cl 2p3/2 [Re2Br2Cl4(P(C2H5)3)2] 198.50  Click
Cl 2p3/2 [RhCl3(P(C6H5)3)3] 198.50  Click
Cl 2p3/2 [RhCl3(P(C6H5)3)3] 198.50  Click
Cl 2p3/2 [PdCl2((NH2)C3NO(CH3)2)] 198.50  Click
Cl 2p3/2 UClO 198.50  Click
Cl 2p3/2 [ReCl(N2)((CH3)2P(C6H5))4] 198.50  Click
Cl 2p3/2 (P(C6H5)3)2ClRuCl3Ru(CO)(P(C6H5)3)2 198.50  Click
Cl 2p3/2 (P(C6H5)3)2ClRuCl3Ru(CS)(P(C6H5)3)2 198.50  Click
Cl 2p3/2 Mo2Cl4(P(CH3)3)4 198.50  Click
Cl 2p3/2 MoWCl4(P(CH3)3)4 198.50  Click
Cl 2p3/2 (-CH(C12H8N)CH2-)n (OC6(CN)2Cl2O)m 198.50  Click
Cl 2p3/2 ZrOCl2 198.50  Click
Cl 2p3/2 TiCl4/W 198.50  Click
Cl 2p3/2 (CH3)3SbCl2 198.51  Click
Cl 2p3/2 [Ru2Cl3(P(C2H5)2-C6H5)6]Cl 198.55  Click
Cl 2p3/2 [PdCl2C6H10] 198.60  Click
Cl 2p3/2 [ReCl3(P(CH3)2C6H5)3] 198.60  Click
Cl 2p3/2 [PdCl2(C3H3NO)2] 198.60  Click
Cl 2p3/2 K2[OsCl6] 198.60  Click
Cl 2p3/2 (C8H12)RhCl2Rh(C8H12) 198.60  Click
Cl 2p3/2 (C8H12)RhCl2Rh(C8H12) 198.60  Click
Cl 2p3/2 [ReCl3(CH3)(N)((CH3)2PC6H5)2] 198.60  Click
Cl 2p3/2 [RhCl2(CH3OC6H4CO)(P(C6H5)3)2] 198.60  Click
Cl 2p3/2 [Rh(NH3)3]Cl3 198.60  Click
Cl 2p3/2 [Rh(NH3)3]Cl3 198.60  Click
Cl 2p3/2 K3[Rh(NO2)3Cl3] 198.60  Click
Cl 2p3/2 K3[Rh(NO2)3Cl3] 198.60  Click
Cl 2p3/2 OsCl3 198.60  Click
Cl 2p3/2 [(C4H9)4N]TcOCl4 198.60  Click
Cl 2p3/2 W2(mu-H)(mu-Cl)Cl4(C2H5C5H5N)4 198.60  Click
Cl 2p3/2 Mo4S4Cl4 198.60  Click
Cl 2p3/2 [Rh2Cl2(P(C6H5)3)4] 198.70  Click
Cl 2p3/2 [N(C2H5)4][InCl2] 198.70  Click
Cl 2p3/2 CuCl2 198.70  Click
Cl 2p3/2 HgCl2 198.70  Click
Cl 2p3/2 K2[PdCl6] 198.70  Click
Cl 2p3/2 [N(C4H9)4]3[Mo2Cl9] 198.70  Click
Cl 2p3/2 [Mo4Cl4Cl4(P(C2H5)3)4] 198.70  Click
Cl 2p3/2 NaCl 198.70  Click
Cl 2p3/2 [As(CH3-C6H4)3]2ClRuCl3RuCl[As(CH3-C6H4)3]2 198.70  Click
Cl 2p3/2 [As(CH3-C6H4)3]3RuCl3RuCl2[As(CH3-C6H4)3] 198.70  Click
Cl 2p3/2 [Tc((C6H5)2PCH2CH2P(C6H5)2)2Cl2]Cl 198.70  Click
Cl 2p3/2 TiCl4/W 198.70  Click
Cl 2p3/2 [As(CH3-C6H4)3]2ClRuCl3RuCl2[As(CH3-C6H4)3] 198.75  Click
Cl 2p3/2 [CdCl2(H2NC(O)NHC(O)NH2)2] 198.80  Click
Cl 2p3/2 Cl2.nH2O 198.80  Click
Cl 2p3/2 [RhCl(C2H4)(P(C6H5)3)2] 198.80  Click
Cl 2p3/2 [PtH(SnCl3)(P(C2H5)3)2] 198.80  Click
Cl 2p3/2 [TiCl(C5H5)2] 198.80  Click
Cl 2p3/2 FeCl2 198.80  Click
Cl 2p3/2 MoCl2 198.80  Click
Cl 2p3/2 K2PdCl4 198.80  Click
Cl 2p3/2 [PdCl2(C6H5CN)2] 198.80  Click
Cl 2p3/2 [RhCl3(CO)3(P(C6H5)3)] 198.80  Click
Cl 2p3/2 K[(N)OsCl4(H2O)] 198.80  Click
Cl 2p3/2 [OsCl2(O)2((C2H5)2P(C6H5))2] 198.80  Click
Cl 2p3/2 [ReCl(CO)((CH3)2P(C6H5))4][FeCl4] 198.80  Click
Cl 2p3/2 LiCl 198.80  Click
Cl 2p3/2 Na[AuCl4] 198.80  Click
Cl 2p3/2 YCl3 198.80  Click
Cl 2p3/2 (-CH(C12H8N)CH2-)n (OC6Cl4O)m 198.80  Click
Cl 2p3/2 (CH3)3SbCl2.SbCl3 198.82  Click
Cl 2p3/2 [SnCl(C6H5)(C6H5C(O)CHC(O)C6H5)2] 198.86  Click
Cl 2p3/2 [RhCl(CO)2(P(C6H5)3)] 198.90  Click
Cl 2p3/2 PdCl2 198.90  Click
Cl 2p3/2 [CuCl2(P(C6H5)4)] 198.90  Click
Cl 2p3/2 [Pd(NH3)2]Cl2 198.90  Click
Cl 2p3/2 [Pd(NH2)2Cl2].2H2O 198.90  Click
Cl 2p3/2 K2[Os(O2)Cl4] 198.90  Click
Cl 2p3/2 [SnCl6(P(C6H5)4)2] 198.90  Click
Cl 2p3/2 PdCl2 198.90  Click
Cl 2p3/2 [PtCl2(C3NO(CH3)2(NH2))2] 199.00  Click
Cl 2p3/2 [N(C3H7)4][InCl4] 199.00  Click
Cl 2p3/2 CaCl2 199.00  Click
Cl 2p3/2 CdCl2 199.00  Click
Cl 2p3/2 FeCl3 199.00  Click
Cl 2p3/2 InCl3 199.00  Click
Cl 2p3/2 [CuCl3(P(C6H5)4)] 199.00  Click
Cl 2p3/2 [ReCl2(N)((C2H5)P(C6H5)2)2] 199.00  Click
Cl 2p3/2 [ReCl(N2)((CH3)2P(C6H5))4]FeCl4 199.00  Click
Cl 2p3/2 PdCl2 199.00  Click
Cl 2p3/2 [AuCl(P(C6H5)3)] 199.05  Click
Cl 2p3/2 [N(C2H5)4][InCl2]Cl2 199.10  Click
Cl 2p3/2 CuCl 199.10  Click
Cl 2p3/2 SrCl2 199.10  Click
Cl 2p3/2 SrCl2 199.10  Click
Cl 2p3/2 PdCl2 199.10  Click
Cl 2p3/2 Os2NCl5 199.10  Click
Cl 2p3/2 W2(mu-H)(mu-Cl)Cl4(C2H5C5H5N)4 199.10  Click
Cl 2p3/2 Ca5(PO4)3Cl 199.10  Click
Cl 2p3/2 CuCl2 199.10  Click
Cl 2p3/2 SrCl2 199.10  Click
Cl 2p3/2 [NH(CH3)3]3[InCl6] 199.20  Click
Cl 2p3/2 [Hg(H2NC(O)NHC(O)NH2)2]Cl2 199.20  Click
Cl 2p3/2 CuCl2 199.20  Click
Cl 2p3/2 MoCl2 199.20  Click
Cl 2p3/2 NiCl2 199.20  Click
Cl 2p3/2 TiCl4 199.20  Click
Cl 2p3/2 TiCl4 199.20  Click
Cl 2p3/2 [ReCl2((CH3)2P(C6H5))2]Cl2 199.20  Click
Cl 2p3/2 W2(mu-H)(mu-Cl)Cl4(C5H5N)4 199.20  Click
Cl 2p3/2 Cs2ZnCl4 199.20  Click
Cl 2p3/2 (ZnCl2)58(CsCl)40(BaCl2)2 199.20  Click
Cl 2p3/2 KCl 199.30  Click
Cl 2p3/2 [SnCl(C6H5)3] 199.30  Click
Cl 2p3/2 [PtCl2(P(C6H5)3)2] 199.30  Click
Cl 2p3/2 cis-[PtCl2(P(C6H5)3)2] 199.30  Click
Cl 2p3/2 (ZnCl2)50(CsCl)40(BaCl2)10 199.30  Click
Cl 2p3/2 (ZnCl2)55(CsCl)40(BaCl2)5 199.30  Click
Cl 2p3/2 ZrCl4 199.30  Click
Cl 2p3/2 CuCl2 199.40  Click
Cl 2p3/2 ZrCl 199.40  Click
Cl 2p3/2 [Mo4Cl4Cl4(P(C4H9)3)4] 199.40  Click
Cl 2p3/2 [Mo4Cl4Cl4(P(C2H5)3)4] 199.40  Click
Cl 2p3/2 (-CH(C12H8N)CH2-)n (OC6Cl4O)m 199.40  Click
Cl 2p3/2 (ZnCl2)50(CsCl)40(BaCl2)10 199.40  Click
Cl 2p3/2 (ZnCl2)58(CsCl)40(BaCl2)2 199.40  Click
Cl 2p3/2 (ZnCl2)55(CsCl)40(BaCl2)5 199.40  Click
Cl 2p3/2 CrCl3 199.40  Click
Cl 2p3/2 [Fe(CH3C(O)CClC(O)CH3)3] 199.50  Click
Cl 2p3/2 MoCl2 199.50  Click
Cl 2p3/2 [Sn(C6H5)2Cl2] 199.50  Click
Cl 2p3/2 ZrCl3 199.50  Click
Cl 2p3/2 TiCl3 199.50  Click
Cl 2p3/2 [Pt2(P(C6H5)3)4SSCH2Cl]Cl 199.50  Click
Cl 2p3/2 [SnCl3(C8H17)(C4H4N2)] 199.60  Click
Cl 2p3/2 [SnCl4(C4H4N2)] 199.60  Click
Cl 2p3/2 [Mo2Cl4(P(C2H5)3)4] 199.60  Click
Cl 2p3/2 [PCl(OC2H5)2] 199.60  Click
Cl 2p3/2 [N(C4H9)4]2[Mo5Cl13] 199.60  Click
Cl 2p3/2 ZnCl2 199.70  Click
Cl 2p3/2 Sc7Cl10C2 199.70  Click
Cl 2p3/2 [SnCl4(C4H4N2)2] 199.80  Click
Cl 2p3/2 (-CH2CH(Cl)-)n 199.80  Click
Cl 2p3/2 Sc2Cl2C 199.80  Click
Cl 2p3/2 Zr2Cl2C 199.80  Click
Cl 2p3/2 ZrCl2 199.80  Click
Cl 2p3/2 [SnCl3(C6H5)(C4H4N2)] 199.90  Click
Cl 2p3/2 [Mo2Cl4(CH3P(C6H5)2)4] 199.90  Click
Cl 2p3/2 MoCl2 199.90  Click
Cl 2p3/2 [Mo6Cl8Cl4(SO(CH3)2)2] 199.90  Click
Cl 2p3/2 [SnCl3(CH3)(C4H4N2)] 199.90  Click
Cl 2p3/2 ScCl3 199.90  Click
Cl 2p3/2 NbCl5 199.90  Click
Cl 2p3/2 [SnCl2(C6H5)2(C4H4N2)] 200.00  Click
Cl 2p3/2 [SnCl3(C4H9)(C4H4N2)] 200.00  Click
Cl 2p3/2 [Sn(C6H5)Cl3] 200.00  Click
Cl 2p3/2 Sc7Cl10 200.00  Click
Cl 2p3/2 (ZnCl2)50(CsCl)40(BaCl2)10 200.00  Click
Cl 2p3/2 (ZnCl2)58(CsCl)40(BaCl2)2 200.00  Click
Cl 2p3/2 (ZnCl2)55(CsCl)40(BaCl2)5 200.00  Click
Cl 2p3/2 [PCl(C6H5)2] 200.10  Click
Cl 2p3/2 (-CH2CH(Cl)-)n 200.10  Click
Cl 2p3/2 CH3Cl/Pt 200.10  Click
Cl 2p3/2 ZnCl2 200.10  Click
Cl 2p3/2 CH3(CH2)2CH(C6H4COCl)(CH2)10CH3 200.20  Click
Cl 2p3/2 ZnCl2 200.20  Click
Cl 2p3/2 MgCl2/Au 200.20  Click
Cl 2p3/2 [PCl2(C6H5)] 200.30  Click
Cl 2p3/2 PCl3 200.30  Click
Cl 2p3/2 ClCH2CH2Br/Pt 200.30  Click
Cl 2p3/2 ClCH2CH2Br/Pt 200.30  Click
Cl 2p3/2 [NiBr(CClCCl2)(P(C2H5)3)2] 200.40  Click
Cl 2p3/2 [Mo6Cl8Cl4(C5H5N)2] 200.40  Click
Cl 2p3/2 [Mo6Cl8Cl4(P(C6H5)3)2] 200.40  Click
Cl 2p3/2 CH3(CH2)13O(C6H4CO)Cl 200.40  Click
Cl 2p3/2 (-CH2CH(C6H4Cl)-)n 200.44  Click
Cl 2p3/2 Ca(ClO)2 200.50  Click
Cl 2p3/2 (-CH2CH(C6H4Cl)-)n 200.50  Click
Cl 2p3/2 MgCl2/Au 200.50  Click
Cl 2p3/2 (-CH2C(CH3)(C(O)OCH2CH2Cl)-)n 200.53  Click
Cl 2p3/2 (-CH2CH(C6H4Cl)-)n 200.53  Click
Cl 2p3/2 NbCl5 200.60  Click
Cl 2p3/2 (-CH2CHC(Cl)CH2-)n 200.63  Click
Cl 2p3/2 (-CH2CH(Cl)-)n 200.64  Click
Cl 2p3/2 (-CCl2CH2-)n 200.78  Click
Cl 2p3/2 [POCl(C2H5O)2] 200.80  Click
Cl 2p3/2 (-CH2CHCl-) (partial unit) 200.80  Click
Cl 2p3/2 (-C-HCH3) (partial unit) 200.81  Click
Cl 2p3/2 C0.795N0.085O0.061Cl0.055 200.90  Click
Cl 2p3/2 C46H30Cl2N6O4 200.90  Click
Cl 2p3/2 C6H5Cl 201.00  Click
Cl 2p3/2 C6H5CCl3 201.00  Click
Cl 2p3/2 (-CH(C12H8N)CH2-)n (OC6Cl4O)m 201.00  Click
Cl 2p3/2 C0.775N0.103O0.067Cl0.060 201.00  Click
Cl 2p3/2 [Co(CH3C(O)CClC(O)CH3)3] 201.10  Click
Cl 2p3/2 (-CH(C12H8N)CH2-)n (OC6Cl4O)m 201.10  Click
Cl 2p3/2 (-CH(C12H8N)CH2-)n (OC6(CN)2Cl2O)m 201.20  Click
Cl 2p3/2 [POCl2(C2H5O)] 201.30  Click
Cl 2p3/2 HSO3Cl 201.40  Click
Cl 2p3/2 [Cu(CH3C(O)CClC(O)CH3)3] 201.50  Click
Cl 2p3/2 Cl3OP 201.70  Click
Cl 2p3/2 [Cr(CH3C(O)CClC(O)CH3)3] 201.90  Click
Cl 2p3/2 NaClO2 203.40  Click
Cl 2p3/2 KClO3 205.90  Click
Cl 2p3/2 Ba(ClO3).H2O 205.90  Click
Cl 2p3/2 Ba(ClO3)2.H2O 205.90  Click
Cl 2p3/2 NaClO3 206.30  Click
Cl 2p3/2 NaClO3 206.40  Click
Cl 2p3/2 NaClO3 206.40  Click
Cl 2p3/2 KClO3 206.50  Click
Cl 2p3/2 KClO3 206.70  Click
Cl 2p3/2 [Co(CH3C(NOH)C(CH3)NCH2CH2NHCH2CH2NHCH2CH2NC(CH3)C(NO)CH3)](ClO4)2 207.00  Click
Cl 2p3/2 Ba(ClO4)2 208.20  Click
Cl 2p3/2 Ba(ClO4)2 208.20  Click
Cl 2p3/2 KClO4 208.30  Click
Cl 2p3/2 CuClO4 208.40  Click
Cl 2p3/2 [Au9(P(C6H5)3)8](ClO4)3 208.55  Click
Cl 2p3/2 Ca(ClO4)2.4H2O 208.60  Click
Cl 2p3/2 NaClO4 208.60  Click
Cl 2p3/2 [Rh(H2O)6](ClO4)3 208.70  Click
Cl 2p3/2 KClO4 208.70  Click
Cl 2p3/2 NaClO4 208.90  Click
Cl 2p3/2 LiClO4 209.40  Click
Cl 2p3/2 LiClO4 209.40  Click

→  Periodic Table 

Six (6) Chemical State Tables of Pt (4f7/2) BEs

 

  • The XPS Library Spectra-Base
  • PHI Handbook
  • Thermo-Scientific Website
  • XPSfitting Website
  • Techdb Website
  • NIST Website

→  Periodic Table 

 

Notes of Caution when using Published BEs and BE Tables from Insulators and Conductors:

  • Accuracy of Published BEs
    • The accuracy depends on the calibration BEs used to calibrate the energy scale of the instrument.  Cu (2p3/2) BE can vary from 932.2 to 932.8 eV for old publications 
    • Different authors use different BEs for the C (1s) BE of the hydrocarbons found in adventitious carbon that appears on all materials and samples.  From 284.2 to 285.3 eV
    • The accuracy depends on when the authors last checked or adjusted their energy scale to produce the expected calibration BEs
  • Worldwide Differences in Energy Scale Calibrations
    • For various reasons authors still use older energy scale calibrations 
    • Some authors still adjust their energy scale so Cu (2p3/2) appears between 932.2 eV or 932.8 eV because this is what the maker taught them
    • This range causes BEs in the higher BE end to be larger than expected 
    • This variation increases significantly above 600 eV BE
  • Charge Compensation
    • Samples that behave as true insulators normally require the use of a charge neutralizer (electron flood gun with or without Ar+ ions) so that the measured chemical state spectra can be produced without peak-shape distortions or sloping tails on the low BE side of the peak envelop. 
    • Floating all samples (conductive, semi-conductive, and non-conductive) and always using the electron flood gun is considered to produce more reliable BEs and is recommended.
  • Charge Referencing Methods for Insulators
    • Charge referencing is a common method, but it can produce results that are less reliable.
    • When an electron flood gun is used, the BE scale will usually shift to lower BE values by 0.01 to 5.0 eV depending on your voltage setting. Normally, to correct for this flood gun induced shift, the BE of the hydrocarbon C (1s) peak maximum from adventitious carbon is used to correct for the charge induced shift.
    • The hydrocarbon peak is normally the largest peak at the lowest BE. 
    • Depending on your preference or training, the C (1s) BE assigned to this hydrocarbon peak varies from 284.8 to 285.0 eV.  Other BEs can be as low as 284.2 eV or as high as 285.3 eV
    • Native oxides that still show the pure metal can suffer differential charging that causes the C (1s) and the O (1s) and the Metal Oxide BE to be larger
    • When using the electron flood gun, the instrument operator should adjust the voltage and the XY position of the electron flood gun to produce peaks from a strong XPS signal (eg O (1s) or C (1s) having the most narrow FWHM and the lowest experimentally measured BE. 

→  Periodic Table 

Table #1

Pt (4f7/2) Chemical State BEs from:  “The XPS Library Spectra-Base”

C (1s) BE = 285.0 eV for TXL BEs
and C (1s) BE = 284.8 eV for NIST BEs

Element Atomic # Compound As-Measured by TXL or NIST Average BE Largest BE Hydrocarbon C (1s) BE  Source
Pt 78 Pt – element 71.0 eV 285.0 eV The XPS Library
Pt 78 Pt/Ni (N*7) 71.1 eV 71.2 eV 284.8 eV Avg BE – NIST
Pt 78 Pt3Ti (N*4) 71.4 eV 71.7 eV 284.8 eV Avg BE – NIST
Pt 78 Pt-Si (N*2) 72.5 eV 73 eV 284.8 eV Avg BE – NIST
Pt 78 Pt-(OH)2 (N*2) 72.6 eV 72.8 eV 284.8 eV Avg BE – NIST
Pt 78 K2PtCl4 (N*6) 72.9 eV 73.4 eV 284.8 eV Avg BE – NIST
Pt 78 K2PtI6 (N*2) 73.4 eV 284.8 eV Avg BE – NIST
Pt 78 Pt-Cl2 (N*1) 73.6 eV 284.8 eV Avg BE – NIST
Pt 78 PtO (N*5) 73.8 eV 74.6 eV 284.8 eV Avg BE – NIST
Pt 78 Pt-O 73.9 eV 285.0 eV The XPS Library
Pt 78 PtO2 (N*6) 74.1 eV 75.6 eV 284.8 eV Avg BE – NIST
Pt 78 PtO(OH)2 (N*1) 74.5 eV 284.8 eV Avg BE – NIST
Pt 78 Pt(OH)4 (N*1) 74.6 eV 284.8 eV Avg BE – NIST
Pt 78 K2Pt(OH)6 (N*2) 75.1 eV 284.8 eV Avg BE – NIST
Pt 78 Pt-O2 75.1 eV 285.0 eV The XPS Library
Pt 78 Pt-Cl4 (N*1) 75.5 eV 284.8 eV Avg BE – NIST
Pt 78 K2PtF6 (N*2) 77.6 eV 284.8 eV Avg BE – NIST

Charge Referencing Notes

  • (N*number) identifies the number of NIST BEs that were averaged to produce the BE in the middle column.
  • The XPS Library uses Binding Energy Scale Calibration with Cu (2p3/2) BE = 932.62 eV and Au (4f7/2) BE = 83.98 eV.  BE (eV) Uncertainty Range:  +/- 0.2 eV
  • Charge Referencing of insulators is defined such that the Adventitious Hydrocarbon C (1s) BE (eV) = 285.0 eV.  NIST uses C (1s) BE = 284.8 eV 
  • Note:   Ion etching removes adventitious carbon, implants Ar (+), changes conductivity of surface, and degrades chemistry of various chemical states.
  • Note:  Ion Etching changes BE of C (1s) hydrocarbon peak.
  • TXL – abbreviation for: “The XPS Library” (https://xpslibrary.com).  NIST:  National Institute for Science and Technology (in USA)

→  Periodic Table 

Table #2

Pt (4f7/2) Chemical State BEs from:  “PHI Handbook”

C (1s) BE = 284.8 eV

→  Periodic Table 

Copyright ©:  Ulvac-PHI

Table #3

Pt (4f7/2) Chemical State BEs from:  “Thermo-Scientific” Website

C (1s) BE = 284.8 eV

Chemical state Binding energy (eV), Pt (4f7/2)
Pt metal 71.0
PtO 72.4
PtO2 74.9

→  Periodic Table 

Copyright ©:  Thermo Scientific 

Table #4

Pt (4f7/2) Chemical State BEs from:  “XPSfitting” Website

Chemical State BE Table derived by Averaging BEs in the NIST XPS database of BEs
C (1s) BE = 284.8 eV

→  Periodic Table 

Copyright ©:  Mark Beisinger

Table #5

Pt (4f7/2) Chemical State BEs from:  “Techdb.podzone.net” Website

 

XPS Spectra – Chemical Shift / Binding Energy
C (1s) BE = 284.6 eV

XPS(X線光電子分光法)スペクトル 化学状態 化学シフト ケミカルシフト

Element Level Compound B.E.(eV) min max
Pt 4f7/2 Pt 71.1 ±0.1 71.0 ～ 71.2
Pt 4f7/2 Pt2Si 72.5 ±0.3 72.2 ～ 72.7
Pt 4f7/2 Pt(OH)2 72.6 ±0.3 72.3 ～ 72.8
Pt 4f7/2 I2Pt(Me3P)2cis 72.6 ±0.3 72.3 ～ 72.8
Pt 4f7/2 Cl2Pt(Ph3P)2cis 72.7 ±0.4 72.3 ～ 73.0
Pt 4f7/2 I2Pt(Me3P)2trans 72.8 ±0.3 72.5 ～ 73.0
Pt 4f7/2 PtSi 73.1 ±0.3 72.8 ～ 73.3
Pt 4f7/2 PtCl2 73.6 ±0.3 73.3 ～ 73.8
Pt 4f7/2 Oxides 74.4 ±0.6 73.8 ～ 75.0
Pt 4f7/2 (IV)Halides 75.5 ±2.1 73.4 ～ 77.6
Pt 4f7/2 PtCl4 75.6 ±0.3 75.3 ～ 75.8

 

→  Periodic Table 

 


Histograms of NIST BEs for Pt (4f7/2) BEs

Important Note:  NIST Database defines Adventitious Hydrocarbon C (1s) BE = 284.8 eV for all insulators.

Histogram indicates:  71.1 eV for Pto based on 31 literature BEs Histogram indicates:  74.9 eV for PtO based on 6 literature BEs

Histogram indicates:  74.8 eV for PtO2 based on 6 literature BEs

Table #6


NIST Database of Pt (4f7/2) Binding Energies

NIST Standard Reference Database 20, Version 4.1

Data compiled and evaluated
by
Alexander V. Naumkin, Anna Kraut-Vass, Stephen W. Gaarenstroom, and Cedric J. Powell
©2012 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved.

Important Note:  NIST Database defines Adventitious Hydrocarbon C (1s) BE = 284.8 eV for all insulators.

 

Element Spectral Line Formula Energy (eV) Reference
Pt 4f7/2 Ag98.9Pt1.1 70.20  Click
Pt 4f7/2 Ag95.8Pt4.2 70.40  Click
Pt 4f7/2 Cu/Pt 70.60  Click
Pt 4f7/2 Cu/Pt 70.60  Click
Pt 4f7/2 Pt 70.61  Click
Pt 4f7/2 CO/Cu/Pt 70.63  Click
Pt 4f7/2 Pt/Cu 70.64  Click
Pt 4f7/2 Pt/CeO2+TiO2 (80-20) 70.70  Click
Pt 4f7/2 Pt 70.72  Click
Pt 4f7/2 CO/Pt 70.72  Click
Pt 4f7/2 O/Pt 70.72  Click
Pt 4f7/2 Pt/CCH3 70.72  Click
Pt 4f7/2 Pt 70.73  Click
Pt 4f7/2 Sn/Pt 70.73  Click
Pt 4f7/2 Sn/Pt 70.73  Click
Pt 4f7/2 Pt 70.74  Click
Pt 4f7/2 Co/Pt 70.74  Click
Pt 4f7/2 H2/Sn/Pt 70.76  Click
Pt 4f7/2 H2/Sn/Pt 70.76  Click
Pt 4f7/2 Pt/Co/Pt 70.81  Click
Pt 4f7/2 Pt 70.83  Click
Pt 4f7/2 Pt/CO 70.83  Click
Pt 4f7/2 Co75Pt25 70.83  Click
Pt 4f7/2 Pt/K 70.84  Click
Pt 4f7/2 Pt 70.87  Click
Pt 4f7/2 Pt 70.90  Click
Pt 4f7/2 Pt 70.90  Click
Pt 4f7/2 Pt 70.90  Click
Pt 4f7/2 Ag5.3Pt94.7 70.90  Click
Pt 4f7/2 CO/Cu/Pt 70.95  Click
Pt 4f7/2 Cu/Pt 70.97  Click
Pt 4f7/2 Cu/Pt 70.97  Click
Pt 4f7/2 Pt 70.99  Click
Pt 4f7/2 Pt 71.00  Click
Pt 4f7/2 Pt 71.00  Click
Pt 4f7/2 Pt/Al2O3 71.00  Click
Pt 4f7/2 Pt(P(C6H5)3)2((CH3)2NC6H4NO) 71.00  Click
Pt 4f7/2 O2/Pt 71.00  Click
Pt 4f7/2 Pt/Cu 71.00  Click
Pt 4f7/2 Pt 71.07  Click
Pt 4f7/2 Pt 71.07  Click
Pt 4f7/2 Pt 71.08  Click
Pt 4f7/2 O2/Pt 71.08  Click
Pt 4f7/2 Co/Pt 71.08  Click
Pt 4f7/2 Pt 71.09  Click
Pt 4f7/2 Pt 71.09  Click
Pt 4f7/2 O2/Pt 71.09  Click
Pt 4f7/2 Pt 71.10  Click
Pt 4f7/2 Pt 71.10  Click
Pt 4f7/2 Pt 71.10  Click
Pt 4f7/2 Pt 71.10  Click
Pt 4f7/2 Pt 71.10  Click
Pt 4f7/2 Pt 71.10  Click
Pt 4f7/2 Pt 71.10  Click
Pt 4f7/2 Pt 71.10  Click
Pt 4f7/2 Pt90Rh10 71.10  Click
Pt 4f7/2 Pt90Rh10 71.10  Click
Pt 4f7/2 Pt/Ni 71.10  Click
Pt 4f7/2 Pt0.042C 71.10  Click
Pt 4f7/2 Pt0.042C 71.10  Click
Pt 4f7/2 Pt0.007C 71.10  Click
Pt 4f7/2 Pt0.007C 71.10  Click
Pt 4f7/2 Pt2.830C 71.10  Click
Pt 4f7/2 Pt2.830C 71.10  Click
Pt 4f7/2 Pt 71.12  Click
Pt 4f7/2 CO/Pt 71.12  Click
Pt 4f7/2 CO/Pt 71.12  Click
Pt 4f7/2 O/Pt 71.12  Click
Pt 4f7/2 Pt/CCH3 71.12  Click
Pt 4f7/2 Pt0.013C 71.12  Click
Pt 4f7/2 Pt0.013C 71.12  Click
Pt 4f7/2 Pt0.012C 71.12  Click
Pt 4f7/2 Pt0.012C 71.12  Click
Pt 4f7/2 Pt 71.13  Click
Pt 4f7/2 Pt 71.13  Click
Pt 4f7/2 Co/Pt 71.13  Click
Pt 4f7/2 Co/Pt 71.13  Click
Pt 4f7/2 Pt/Co/Pt 71.13  Click
Pt 4f7/2 Pt/Co/Pt 71.13  Click
Pt 4f7/2 Pt 71.14  Click
Pt 4f7/2 Pt0.011C 71.14  Click
Pt 4f7/2 Pt0.011C 71.14  Click
Pt 4f7/2 Pt/Ni 71.15  Click
Pt 4f7/2 Pt/Ni 71.15  Click
Pt 4f7/2 Pt 71.20  Click
Pt 4f7/2 Pt 71.20  Click
Pt 4f7/2 Pt 71.20  Click
Pt 4f7/2 Pt 71.20  Click
Pt 4f7/2 Pt 71.20  Click
Pt 4f7/2 Pt90Rh10 71.20  Click
Pt 4f7/2 Pt/Ni 71.20  Click
Pt 4f7/2 Pt/Ni 71.20  Click
Pt 4f7/2 Pt/Ni 71.20  Click
Pt 4f7/2 Ag98.9Pt1.1 71.20  Click
Pt 4f7/2 Pt/Si 71.22  Click
Pt 4f7/2 Pt/Ni 71.25  Click
Pt 4f7/2 [Pt(CH3)2(P(C6H5)3)2] 71.30  Click
Pt 4f7/2 Pt 71.30  Click
Pt 4f7/2 Pt 71.30  Click
Pt 4f7/2 Pt 71.30  Click
Pt 4f7/2 Pt 71.30  Click
Pt 4f7/2 Pt 71.30  Click
Pt 4f7/2 Pt3Ti 71.30  Click
Pt 4f7/2 Pt/CeO2+TiO2 (20-80) 71.30  Click
Pt 4f7/2 O2/Pt3Ti 71.30  Click
Pt 4f7/2 O2/Pt3Ti 71.30  Click
Pt 4f7/2 O2/Pt3Ti 71.30  Click
Pt 4f7/2 Pt84Re16 71.31  Click
Pt 4f7/2 O/Pt 71.34  Click
Pt 4f7/2 Co75Pt25 71.36  Click
Pt 4f7/2 Co75Pt25 71.38  Click
Pt 4f7/2 [Pt(P(C6H5)3)3] 71.40  Click
Pt 4f7/2 [Pt(P(C6H5)3)3] 71.40  Click
Pt 4f7/2 [Pt((C6H5)3P)4] 71.40  Click
Pt 4f7/2 Pt3Ti 71.40  Click
Pt 4f7/2 O2/Pt3Ti 71.40  Click
Pt 4f7/2 Pt(P(C6H5)3)4 71.40  Click
Pt 4f7/2 [(C6H5)3P]3Pt 71.40  Click
Pt 4f7/2 Co/Pt 71.40  Click
Pt 4f7/2 Pt83Re17 71.44  Click
Pt 4f7/2 Pt/CCH3 71.48  Click
Pt 4f7/2 Pt/CeO2+TiO2 (80-20) 71.50  Click
Pt 4f7/2 Pt(P(C6H5)3)4 71.50  Click
Pt 4f7/2 [(Pt(P(C6H5)3)2S)2PtCl2] 71.50  Click
Pt 4f7/2 Pt/Co/Pt 71.56  Click
Pt 4f7/2 Pt/Co/Pt 71.56  Click
Pt 4f7/2 H2/Sn/Pt 71.57  Click
Pt 4f7/2 H2/Sn/Pt 71.57  Click
Pt 4f7/2 Pt3Ti 71.60  Click
Pt 4f7/2 Pt/CeO2+TiO2 (20-80) 71.60  Click
Pt 4f7/2 Re/Pt 71.60  Click
Pt 4f7/2 Co/Pt 71.60  Click
Pt 4f7/2 Pt73Re27 71.63  Click
Pt 4f7/2 Pt3Ti 71.65  Click
Pt 4f7/2 CO/Pt3Ti 71.65  Click
Pt 4f7/2 Pt3Ti 71.70  Click
Pt 4f7/2 Pt4H3Na45(AlO2)56(SiO2)136 71.70  Click
Pt 4f7/2 [Pt2(SP(C6H5)2)2(P(C6H5)3)2] 71.80  Click
Pt 4f7/2 [Pt(SP(C6H5)3)(P(C6H5)2)] 71.80  Click
Pt 4f7/2 Cl2(C5H5N)(CH2C5H5N)Pt 71.80  Click
Pt 4f7/2 [Pt(AuP(C6H5)3)8](NO3)2 71.80  Click
Pt 4f7/2 Pt53Re47 71.84  Click
Pt 4f7/2 K2[Pt(SCN)4] 71.90  Click
Pt 4f7/2 (C6H4S4)2(C6H4S4)[Pt(S2C2O2)2] 71.90  Click
Pt 4f7/2 [P(C6H5)3Pt(AuP(C6H5)3)6](NO3)2 71.90  Click
Pt 4f7/2 [P(C6H5)3HPt(AuP(C6H5)3)7](NO3)2 71.90  Click
Pt 4f7/2 Pt3(CO)Cl((C6H5)2PCH2P(C6H5)2)3[PF6] 71.90  Click
Pt 4f7/2 Pt4H7Na41(AlO2)56(SiO2)136 71.90  Click
Pt 4f7/2 Pt4H11Na37(AlO2)56(SiO2)136 71.90  Click
Pt 4f7/2 Pt39Re61 71.98  Click
Pt 4f7/2 [Pt3(CO)3(C6H11PH2)3] 72.00  Click
Pt 4f7/2 N(C2H5)4[Pt(S2C2O2)2] 72.00  Click
Pt 4f7/2 [P(C6H5)3Pt(AuP(C6H5)3)6(HgNO3)]NO3 72.00  Click
Pt 4f7/2 [IP(C6H5)3Pt(AuP(C6H5)3)4]BF4 72.00  Click
Pt 4f7/2 [(P(C6H5)3)2Pt(AuP(C6H5)3)3]PF6 72.00  Click
Pt 4f7/2 Pt4H20Na28(AlO2)56(SiO2)136 72.00  Click
Pt 4f7/2 (C6H4S4)2[Pt(S2C2O2)2] 72.05  Click
Pt 4f7/2 [PtCl2(P(C4H9)3)2] 72.10  Click
Pt 4f7/2 [N(C2H5)4]2[Pt(B10H12)2] 72.10  Click
Pt 4f7/2 ((CH3)2(CH3(CH2)17)2N)Pt(Cl)6/SiO2 72.10  Click
Pt 4f7/2 [(Pt(P(C6H5)3)2S)2] 72.10  Click
Pt 4f7/2 CO/Pt 72.13  Click
Pt 4f7/2 [Pt(CH3)2(P(C2H5)3)2] 72.20  Click
Pt 4f7/2 [Pt(C2H4)(P(C6H5)3)2] 72.20  Click
Pt 4f7/2 [Pt2Cl2((C6H5)2PCH2P(C6H5)2)2] 72.20  Click
Pt 4f7/2 [PtCl2(CH3SCH2CH2CH(NH2)COOH)] 72.20  Click
Pt 4f7/2 [Pt((C6H5)2PCH2P(C6H5)2)(CH3)2] 72.20  Click
Pt 4f7/2 [N(C2H5)4][Pt((C6H5)C(S)C(S)(C6H5))2] 72.20  Click
Pt 4f7/2 [(C2H5)3P]2Pt(CH3)2 72.20  Click
Pt 4f7/2 [Pt((C2H5)2NC(S)S)2] 72.30  Click
Pt 4f7/2 [PtCl2(P(C6H5)3)2] 72.30  Click
Pt 4f7/2 cis-[PtCl2(P(C6H5)3)2] 72.30  Click
Pt 4f7/2 PtOSn 72.30  Click
Pt 4f7/2 Pt3(CO)(SnF3)((C6H5)2PCH2P(C6H5)2)3[PF6] 72.30  Click
Pt 4f7/2 [P(C6H5)3COPt(AuP(C6H5)3)5]Cl 72.30  Click
Pt 4f7/2 [P(C6H5)3Pt(AuP(C6H5)3)5(HgNO3)2]NO3 72.30  Click
Pt 4f7/2 [P(C6H5)3CNPt(AuP(C6H5)3)6]NO3 72.30  Click
Pt 4f7/2 [PtBr2((CH3NCH)NHNH(CHNCH3))] 72.40  Click
Pt 4f7/2 [Pt(C2H2)(P(C6H5)3)2] 72.40  Click
Pt 4f7/2 (NH4)2[PtCl4] 72.40  Click
Pt 4f7/2 PtO 72.40  Click
Pt 4f7/2 [AuPt3(CO)3(C6H11PH2)4].PF6 72.40  Click
Pt 4f7/2 [(Pt(P(C6H5)3)2S)2PtCl2] 72.40  Click
Pt 4f7/2 [PtI2(P(C2H5)3)2] 72.50  Click
Pt 4f7/2 [Pt(H2NC(O)NHC(O)NH2)2]Cl2 72.50  Click
Pt 4f7/2 [Pt((C6H5)CSSC(C6H5))2] 72.50  Click
Pt 4f7/2 [Pt(C2H4)(P(C6H5)3)2] 72.50  Click
Pt 4f7/2 [Pt(C6H5)2(P(C2H5)3)2] 72.50  Click
Pt 4f7/2 Pt2Si 72.50  Click
Pt 4f7/2 [(C2H5)3P]2Pt(C6H5)2 72.50  Click
Pt 4f7/2 Pt3(SnF3)2((C6H5)2PCH2P(C6H5)2)3[PF6] 72.50  Click
Pt 4f7/2 Pt/Si 72.50  Click
Pt 4f7/2 [(CO)3(P(C6H5)3)4Pt3(AuP(C6H5)3)]NO3 72.50  Click
Pt 4f7/2 [Pt3(Re(CO)3))((C6H5)2PCH2P(C6H5)2)3][PF6] 72.50  Click
Pt 4f7/2 [Pt3(Re(CO)3))O((C6H5)2PCH2P(C6H5)2)3][PF6] 72.50  Click
Pt 4f7/2 PtS 72.55  Click
Pt 4f7/2 [PtI2(P(CH3)3)2] 72.60  Click
Pt 4f7/2 [PtClCH3(P(C2H5)3)2] 72.60  Click
Pt 4f7/2 K2[PtBr4] 72.60  Click
Pt 4f7/2 K2[PtBr4] 72.60  Click
Pt 4f7/2 Pt(OH)2 72.60  Click
Pt 4f7/2 [PtClH(P(C2H5)3)2] 72.60  Click
Pt 4f7/2 [(C2H5)3P]2PtHCl 72.60  Click
Pt 4f7/2 [(C2H5)3P]2PtCH3Cl 72.60  Click
Pt 4f7/2 [(C6H5)2PCH2CH2P(C6H5)2Pt(AuP(C6H5)3)4](PF6)2 72.60  Click
Pt 4f7/2 [CNPt(AuP(C6H5)3)8AuCN]NO3 72.60  Click
Pt 4f7/2 [CN(CH3)2C6H3Pt(AuP(C6H5)3)8](NO3)2 72.60  Click
Pt 4f7/2 [Pt2(P(C6H5)3)4SSCH3]I 72.60  Click
Pt 4f7/2 [(Pt2(P(C6H5)3)4S2Cu)2(mu-dppf)][PF6]2 72.60  Click
Pt 4f7/2 ((CH3)2(CH3(CH2)17)2N)Pt(Cl)6/SiO2 72.60  Click
Pt 4f7/2 [(Pt(P(C6H5)3)2S)2Au(P(C6H5)3)]PF6 72.60  Click
Pt 4f7/2 (C8H12)PtCl2 72.65  Click
Pt 4f7/2 [PtI2(P(CH3)3)2] 72.70  Click
Pt 4f7/2 [PtCl2(P(C2H5)3)2] 72.70  Click
Pt 4f7/2 [PtCl2(O2)(C10H8N2)] 72.70  Click
Pt 4f7/2 Pt3(CO)((C6H5)2PCH2P(C6H5)2)3[PF6]2 72.70  Click
Pt 4f7/2 [Pt2(P(C6H5)3)4SSCHCl2]PF6 72.70  Click
Pt 4f7/2 [(Pt2(P(C6H5)3)4S2Pd)2Cl2][PF6]2 72.70  Click
Pt 4f7/2 [(Pt2(P(C6H5)3)4S2)2Ag2][NO3]2 72.70  Click
Pt 4f7/2 [Pt(C2F4)(P(C6H5)3)2] 72.80  Click
Pt 4f7/2 [Pt(C2H4)(P(C6H5)3)2] 72.80  Click
Pt 4f7/2 [Pt2S2(P(C6H5)3)4] 72.80  Click
Pt 4f7/2 [Pt(-C-6H5S)2] 72.80  Click
Pt 4f7/2 Pt(OH)2 72.80  Click
Pt 4f7/2 Pt/CeO2+TiO2 (20-80) 72.80  Click
Pt 4f7/2 [(Pt(P(C6H5)3)2S)2Hg(C6H5)2PCH2CH2P(C6H5)2)][PF6]2 72.80  Click
Pt 4f7/2 [(Pt2(P(C6H5)3)4S2)2Hg][PF6]2 72.80  Click
Pt 4f7/2 [Pt2(P(C6H5)3)4SSCH2Cl]Cl 72.80  Click
Pt 4f7/2 Pt/Si 72.82  Click
Pt 4f7/2 K2PtCl4 72.90  Click
Pt 4f7/2 K2PtCl4 72.90  Click
Pt 4f7/2 [Pt2(NH3)4(C5H4ON)2]2(NO3)5 72.90  Click
Pt 4f7/2 [PtCl2(P(C6H5)3)2] 72.90  Click
Pt 4f7/2 [Pt3(ReO3)((C6H5)2PCH2P(C6H5)2)3][PF6]CH2Cl2 72.90  Click
Pt 4f7/2 [Pt3(Re(CO)3))O3((C6H5)2PCH2P(C6H5)2)3][PF6] 72.90  Click
Pt 4f7/2 [Pt2(P(C6H5)3)4SSCH2C6H5]PF6 72.90  Click
Pt 4f7/2 [Pt3(Re(CO)3))O2((C6H5)2PCH2P(C6H5)2)3][PF6]OC2H5 72.90  Click
Pt 4f7/2 [PtB10H12(P(C6H5)3)2] 73.00  Click
Pt 4f7/2 [PtCl(C2Cl3)(P(C6H5)3)2] 73.00  Click
Pt 4f7/2 [Pt(C(HNCH3)2)4(PF6)2] 73.00  Click
Pt 4f7/2 K2PtCl4 73.00  Click
Pt 4f7/2 K2PtCl4 73.00  Click
Pt 4f7/2 [PtBr4(C4H10N4)] 73.00  Click
Pt 4f7/2 [PtCl2(H2NC2H4NH2)2] 73.00  Click
Pt 4f7/2 [Pt(O2)((C6H5)3P)2] 73.00  Click
Pt 4f7/2 [PtCl2(P(C6H5)3)2] 73.00  Click
Pt 4f7/2 cis-[PtCl2(P(C6H5)3)2] 73.00  Click
Pt 4f7/2 [Pt(H2NC2H4NH2)2][PtCl2(H2NC2H4NH2)2](ClO4)2 73.00  Click
Pt 4f7/2 [N(C2H5)4]3[Pt(SnCl3)5] 73.00  Click
Pt 4f7/2 PtSi 73.00  Click
Pt 4f7/2 [(Pt(P(C6H5)3)2S)2Ni(C6H5)2PCH2CH2P(C6H5)2)][PF6]2 73.00  Click
Pt 4f7/2 (-Pt((C4H9)3P)2-C&=C-C6H4-C6H4-C&=C-)n 73.00  Click
Pt 4f7/2 [PtCl2(P(C2H5)3)2] 73.10  Click
Pt 4f7/2 [PtCl4((CH3NCH)NHNH(CHNCH3))] 73.10  Click
Pt 4f7/2 [PtCl2(CH2(P(C6H5)2)2)] 73.10  Click
Pt 4f7/2 [PtCl2(NH(C6H5)NHC(S)SCH3)2] 73.10  Click
Pt 4f7/2 K2PtCl4 73.10  Click
Pt 4f7/2 [N(CH3)4]2[Pt(SnCl3)5] 73.10  Click
Pt 4f7/2 [PtCl2(P(C6H5)3)2] 73.10  Click
Pt 4f7/2 [Pt(NH3)2]Cl2 73.10  Click
Pt 4f7/2 Pt/CeO2+TiO2 (80-20) 73.10  Click
Pt 4f7/2 [Pt(NH2(CH2)2NH(CH2)2NH2)NO3]NO3 73.10  Click
Pt 4f7/2 Pt((C4H9)3P)2Cl2 73.10  Click
Pt 4f7/2 [PtCl2(C6H5)2PCH2CH2P(C6H5)2] 73.10  Click
Pt 4f7/2 [Pt(SCN)4(P(C6H5)4)2] 73.20  Click
Pt 4f7/2 [N(CH3)4]2[PtCl2(SnCl3)2] 73.20  Click
Pt 4f7/2 [PtCl2(P(C6H5)3)2] 73.20  Click
Pt 4f7/2 cis-[PtCl2(P(C6H5)3)2] 73.20  Click
Pt 4f7/2 [Pt(NH3)2]Cl2 73.20  Click
Pt 4f7/2 [Pt(NH3)2]Cl2 73.20  Click
Pt 4f7/2 K2PtCl4 73.20  Click
Pt 4f7/2 Pt(C32H16N8) 73.20  Click
Pt 4f7/2 Pt(C32H16N8)(AsF6)x 73.20  Click
Pt 4f7/2 Pt(C32H16N8)(AsF6)x 73.20  Click
Pt 4f7/2 Pt(C32H16N8)(ClO4)0.5 73.20  Click
Pt 4f7/2 C32H16N8Pt(AsF6)0.5 73.20  Click
Pt 4f7/2 C32H16N8Pt(ClO4)0.5 73.20  Click
Pt 4f7/2 C32H16N8Pt 73.20  Click
Pt 4f7/2 PtCl2((C6H5)2PCH2P(C6H5)2) 73.20  Click
Pt 4f7/2 PtCl2 73.20  Click
Pt 4f7/2 [Pt3(ReO3)O3((C6H5)2PCH2P(C6H5)2)3][PF6] 73.20  Click
Pt 4f7/2 [PtCl2(C3NO(CH3)2(NH2))2] 73.30  Click
Pt 4f7/2 [Pt(NH2NH2ClC(S)SCH3)2] 73.30  Click
Pt 4f7/2 [PtBr2((CH3)C3HNO(C6H5))2] 73.30  Click
Pt 4f7/2 [Pt(NH2(CH2)2NH(CH2)2NH2)Cl]Cl 73.30  Click
Pt 4f7/2 [Pt(B10H12)(P(C2H5)3)2] 73.40  Click
Pt 4f7/2 [Pt2(CNCH3)6(PF6)2] 73.40  Click
Pt 4f7/2 K2PtCl4 73.40  Click
Pt 4f7/2 K2PtCl4 73.40  Click
Pt 4f7/2 Pt(NH3)4Br2 73.40  Click
Pt 4f7/2 Pt(NH3)4Br2 73.40  Click
Pt 4f7/2 Pt(NH3)4Cl2 73.40  Click
Pt 4f7/2 Pt(NH3)4Cl2 73.40  Click
Pt 4f7/2 [Pt(H2NC2H4NH2)2][PtI2(H2NC2H4NH2)2](ClO4)2 73.40  Click
Pt 4f7/2 K2PtI6 73.40  Click
Pt 4f7/2 K2PtI6 73.40  Click
Pt 4f7/2 K4[Pt2(P2O5H2)4I].nH2O 73.40  Click
Pt 4f7/2 PtNH3Cl2 73.40  Click
Pt 4f7/2 [Pt2(NCCH3)6].(BF4)2 73.50  Click
Pt 4f7/2 [PtCl2((CH3)C3HNO(C6H5))2] 73.50  Click
Pt 4f7/2 [PtBr2(C3HNO(C6H5)2)2] 73.50  Click
Pt 4f7/2 K4[Pt2(P2O5H2)4].3H2O 73.50  Click
Pt 4f7/2 PtCl2 73.60  Click
Pt 4f7/2 [Pt(CH3CONH)2].H2O 73.60  Click
Pt 4f7/2 [Pt(CH3CONH)2].H2O 73.60  Click
Pt 4f7/2 [PtCl2(C3HNO(C6H5)2)2] 73.60  Click
Pt 4f7/2 K4[Pt2(P2O5H2)4Cl].3H2O 73.60  Click
Pt 4f7/2 [Pt(CN)2(P(C2H5)3)2] 73.70  Click
Pt 4f7/2 [Pt(NH3)2(NO2)2] 73.70  Click
Pt 4f7/2 [Pt(NH3)2(NO2)2] 73.70  Click
Pt 4f7/2 Pt/CeO2+TiO2 (20-80) 73.70  Click
Pt 4f7/2 [Pt(S(NH)C6H4)2] 73.70  Click
Pt 4f7/2 [(C2H5)3P]2Pt(CN)2 73.70  Click
Pt 4f7/2 K4[Pt2(P2O5H2)4Br].3H2O 73.70  Click
Pt 4f7/2 [Pt(C2H3O2)2] 73.80  Click
Pt 4f7/2 PtO 73.80  Click
Pt 4f7/2 K2Pt(CN)4 73.80  Click
Pt 4f7/2 [PtCl2(C8H12)] 73.90  Click
Pt 4f7/2 Pt/CeO2+TiO2 (20-80) 73.90  Click
Pt 4f7/2 [PtCl4(C2H5NH2)4] 74.10  Click
Pt 4f7/2 [PtCl2(C8H12)] 74.10  Click
Pt 4f7/2 K2[Pt(NO2)4] 74.10  Click
Pt 4f7/2 K2[Pt(NO2)4] 74.10  Click
Pt 4f7/2 PtO2 74.10  Click
Pt 4f7/2 PtS2 74.16  Click
Pt 4f7/2 K2PtCl4 74.20  Click
Pt 4f7/2 K2[Pt(CN)4].3H2O 74.20  Click
Pt 4f7/2 PtO 74.20  Click
Pt 4f7/2 PtO 74.20  Click
Pt 4f7/2 [Pt(H2NC2H4NH2)2][PtI2(H2NC2H4NH2)2](ClO4)2 74.30  Click
Pt 4f7/2 [PtCl6(-NHC(CH3)C(OH)C(CH2OH)C(CH2OH)CH-)2] 74.40  Click
Pt 4f7/2 [Pt(NH3)2(NO2)2] 74.40  Click
Pt 4f7/2 Pt(OH)2O 74.50  Click
Pt 4f7/2 Pt(SO4)2.nH2O 74.60  Click
Pt 4f7/2 [PtI2(CH3C(O)NH)4] 74.60  Click
Pt 4f7/2 Pt(OH)4 74.60  Click
Pt 4f7/2 K2PtBr6 74.60  Click
Pt 4f7/2 K2PtBr6 74.60  Click
Pt 4f7/2 PtO2 74.60  Click
Pt 4f7/2 PtO 74.60  Click
Pt 4f7/2 PtO 74.60  Click
Pt 4f7/2 O2/Pt3Ti 74.60  Click
Pt 4f7/2 [Pt(NH2(CH2)2NH(CH2)2NH2)CN]I 74.60  Click
Pt 4f7/2 [Pt(NH2(CH2)2NH(CH2)2NH2)NO2]I 74.60  Click
Pt 4f7/2 [Pt(NH2(CH2)2NH(CH2)2NH2)I]I 74.70  Click
Pt 4f7/2 [PtCl2(CH3C(O)NH)4] 74.80  Click
Pt 4f7/2 [Pt2Br2(CH3C(O)NH)4] 74.90  Click
Pt 4f7/2 PtO2 74.90  Click
Pt 4f7/2 PtO2 74.90  Click
Pt 4f7/2 [Pt(CH3CN)4(PF6)2] 75.00  Click
Pt 4f7/2 [Pt2(NO3)2(CH3C(O)NH)4] 75.00  Click
Pt 4f7/2 [Pt(NO3)2(CH3C(O)NH)4] 75.00  Click
Pt 4f7/2 [Pt(NO2)2(CH3C(O)NH)4] 75.00  Click
Pt 4f7/2 [Pt(H2NC2H4NH2)2][PtCl2(H2NC2H4NH2)2](ClO4)2 75.00  Click
Pt 4f7/2 PtO2 75.00  Click
Pt 4f7/2 K2Pt(OH)6 75.10  Click
Pt 4f7/2 K2Pt(OH)6 75.10  Click
Pt 4f7/2 [PtI2((NH2)2CHCH3)2][Pd((NH2)2CHCH3)2](ClO4)4 75.20  Click
Pt 4f7/2 K2[PtCl6] 75.20  Click
Pt 4f7/2 [PtCl4(P(C2H5)3)2] 75.30  Click
Pt 4f7/2 [PtCl2(H2NCH2CH2NH2)2]Cl2 75.30  Click
Pt 4f7/2 [PtBr2((NH2)2CHCH3)2][Ni((NH2)2CHCH3)2](ClO4)4 75.40  Click
Pt 4f7/2 K2[PtCl6] 75.40  Click
Pt 4f7/2 [Pd(H2NC2H4NH2)2][PtBr2(H2NC2H4NH2)2](ClO4)4 75.40  Click
Pt 4f7/2 K[PtCl6] 75.40  Click
Pt 4f7/2 PtO2 75.40  Click
Pt 4f7/2 [Pt2(C2H3O2)6] 75.50  Click
Pt 4f7/2 PtCl4 75.50  Click
Pt 4f7/2 K2[PtCl6] 75.50  Click
Pt 4f7/2 K2[PtCl6] 75.50  Click
Pt 4f7/2 K2[PtCl6] 75.50  Click
Pt 4f7/2 [PtCl2((NH2)2CHCH3)2][Ni((NH2)2CHCH3)2](ClO4)4 75.60  Click
Pt 4f7/2 [PtCl2((NH2)2CHCH3)2][Pd((NH2)2CHCH3)2](ClO4)4 75.60  Click
Pt 4f7/2 [PtCl2(H2NCH2CH2NH2)2]Cl2 75.60  Click
Pt 4f7/2 K2[PtCl6] 75.60  Click
Pt 4f7/2 PtO2 75.60  Click
Pt 4f7/2 [PtClH(P(C2H5)3)2] 75.70  Click
Pt 4f7/2 K2PtCl6 75.70  Click
Pt 4f7/2 [PtCl4(P(C2H5)3)2] 75.90  Click
Pt 4f7/2 [PtCl4(P(C2H5)3)2] 75.90  Click
Pt 4f7/2 [PtHCl(P(C6H5)3)2] 75.90  Click
Pt 4f7/2 K2[Pt(NO2)6] 75.90  Click
Pt 4f7/2 K2[Pt(NO2)6] 75.90  Click
Pt 4f7/2 [(C2H5)3P]2PtCl4 75.90  Click
Pt 4f7/2 PtCl4 75.90  Click
Pt 4f7/2 K2[Pt(NO2)3(NO3)3] 76.00  Click
Pt 4f7/2 [PtCl2(P(C2H5)3)2] 76.20  Click
Pt 4f7/2 [PtH(SnCl3)(P(C2H5)3)2] 76.20  Click
Pt 4f7/2 [Pt(NH3)6]Cl4 76.30  Click
Pt 4f7/2 [Pt(NH3)6]Cl4 76.30  Click
Pt 4f7/2 [PtCl2(P(C6H5)3)2] 76.30  Click
Pt 4f7/2 [PtCl2(P(C2H5)3)2] 76.40  Click
Pt 4f7/2 [PtCl2(C2H5NH2)4].4H2O 76.40  Click
Pt 4f7/2 K2[PtCl2(CN)4].3H2O 76.60  Click
Pt 4f7/2 K2PtF6 77.60  Click
Pt 4f7/2 K2PtF6 77.60  Click

 


Statistical Analysis of Binding Energies in NIST XPS Database of BEs