Feo FeO α-Fe2O3 γ-Fe2O3 Fe3O4 α-FeO(OH) FeCO3 FeC K3Fe(CN)6 Fe4N FeS FeS2 Fe2(SO4)3 FeCl2 FeF2 FeF3 Basic

XPS Spectra
Iron (Fe) Compounds
The XPS Spectra section provides raw and processed survey spectra, chemical state spectra, BE values, FWHM values, and overlays of key spectra.
Atom% values from surveys are based on sample, as received, and Scofield cross-sections. Atom% values are corrected for IMFP and PE.
Peak-fits are guides for practical, real-world applications. Peak-fits are not fully optimized or designed to test any theory.


Iron Oxide (Fe3O4 – Magnetite)
Survey, Peak-fits, BEs, FWHMs, and Peak Labels


 Periodic Table   → Six (6) BE Tables
Survey Spectrum from Fe3O4
Freshly exposed bulk, Flood gun is OFF, C (1s) BE = 284.9 eV, Ag (3d5/2) FWHM = 1.3 eV
 


 Periodic Table  → Six (6) BE Tables
Fe (2p3/2) Spectrum from Fe3O4 Raw
Fresh exposed bulk, Flood gun is OFF, C (1s) BE = 284.9 eV, Ag FWHM = 0.75 eV
Fe (2p3/2) Spectrum from Fe3O4 Peak-Fit
Freshly exposed bulk, Flood gun is OFF, C (1s) BE = 284.9 eV, Ag FWHM = 0.75 eV

   
Fe (2p) Raw – Range: 702 – 742 eV
Fresh exposed bulk, Flood gun is OFF, C (1s) BE = 284.9 eV, Ag FWHM = 0.75 eV
Fe (2p) Peak-fit – Range: 702 – 742 eV
Fresh exposed bulk, Flood gun is OFF, C (1s) BE = 284.9 eV, Ag FWHM = 0.75 eV
 
Fe (2p) Raw – Range: 702 – 772 eV
Fresh exposed bulk, Flood gun is OFF, C (1s) BE = 284.9 eV, Ag FWHM = 0.75 eV
Fe (2p) Peak-fit – Range: 702 – 772 eV
Fresh exposed bulk, Flood gun is OFF, C (1s) BE = 284.9 eV, Ag FWHM = 0.75 eV

 Periodic Table  → Six (6) BE Tables
O (1s) Spectrum from Fe3O4 Raw
Freshly exposed bulk, Flood gun is OFF, C (1s) BE = 284.9 eV, Ag FWHM = 0.75 eV
O (1s) Spectrum from Fe3O4 Peak-Fit
Freshly exposed bulk, Flood gun is OFF, C (1s) BE = 284.9 eV, Ag FWHM = 0.75 eV
Vertical Expansion of O (1s) Spectrum from Fe3O4 Raw Vertical Expansion of O (1s) Spectrum from Fe3O4Peak-fit
Vertical Expansion of O (1s) Spectrum from Fe3O4 Raw Vertical Expansion of O (1s) Spectrum from Fe3O4Peak-fit

 Periodic Table  → Six (6) BE Tables
C (1s) Spectrum from Fe3O4 Raw
Freshly exposed bulk, Flood gun is OFF, C (1s) BE = 284.9 eV, Ag FWHM = 0.75 eV
C (1s) Spectrum from Fe3O4 Peak-Fit
Freshly exposed bulk, Flood gun is OFF, C (1s) BE = 284.9 eV, Ag FWHM = 0.75 eV

 Periodic Table  → Six (6) BE Tables
Fe (3p) Spectrum from Fe3O4 Raw
Freshly exposed bulk, Flood gun is OFF, C (1s) BE = 284.9 eV, Ag FWHM = 0.75 eV
Fe (3p) Spectrum from Fe3O4 Peak-Fit
Freshly exposed bulk, Flood gun is OFF, C (1s) BE = 284.9 eV, Ag FWHM = 0.75 eV

 Periodic Table  → Six (6) BE Tables
Fe (3s) Spectrum from Fe3O4 Raw
Freshly exposed bulk, Flood gun is OFF, C (1s) BE = 284.9 eV, Ag FWHM = 0.75 eV
Fe (3s) Spectrum from Fe3O4 Peak-Fit
Freshly exposed bulk, Flood gun is OFF, C (1s) BE = 284.9 eV, Ag FWHM = 0.75 eV

 Periodic Table  → Six (6) BE Tables
Auger Signals from Fe3O4 Raw
Freshly exposed bulk, Flood gun is OFF, C (1s) BE = 284.9 eV, Ag FWHM = 0.75 eV
Valence Band Signals from Fe3O4 Raw
Freshly exposed bulk, Flood gun is OFF, C (1s) BE = 284.9 eV, Ag FWHM = 0.75 eV

 
Overlays
 Periodic Table  → Six (6) BE Tables
Valence Band SpectraOverlay of Fe2O3 and Fe3O4
Freshly exposed bulk, Flood gun is OFF, C (1s) BE = 284.9 eV, Ag FWHM = 0.75 eV
Fe (2p) SpectraOverlay of Fe2O3 and Fe3O4
Freshly exposed bulk, Flood gun is OFF, C (1s) BE = 284.9 eV, Ag FWHM = 0.75 eV
Overlay of Fe (2p) from Fe2O3, Fe3O4 and FeO(OH)
Overlay of Fe (2p) from Fe2O3, Fe3O4, FeO and FeO(OH)


End-of-spectra-page

Price to purchase raw data sets:
Raw spectra – VAMAS ASCII format ($6)
Raw spectra – SDP binary format ($5)
SDP v9 – $175 (2 yr license)

Transmission Function Tests


 

December 2015 – Transmission Function of Thermo K-Alpha Plus

 Periodic Table 
Survey Spectra of Ion Etched Copper (Cu), PEs = 50, 100, 150 and 200 eV

 Periodic Table 
March 2016 – Transmission Function of Thermo K-Alpha Plus 
 
Survey Spectra of Ion Etched Copper (Cu), PEs = 100, 150 and 200 eV

 Periodic Table  
August 2019 – Transmission Function of Thermo K-Alpha Plus
 
Survey Spectra of HOPG (C), PEs = 20, 50, 100 and 200 eV

 Periodic Table  
January 2022 – Transmission Function of Thermo K-Alpha Plus
Survey Spectra of Ion Etched Copper (Cu), PEs = 100, 120, 140, 160, 180 and 200 eV


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