Pto PtO2 PtCl4 PtS2 PtMn Pt/Zeolite Pt/C Basic 

XPS Spectra
Platinum (Pt) Compounds
The XPS Spectra section provides raw and processed survey spectra, chemical state spectra, BE values, FWHM values, and overlays of key spectra.
Atom% values from surveys are based on sample, as received, and Scofield cross-sections. Atom% values are corrected for IMFP and PE.
Peak-fits are guides for practical, real-world applications. Peak-fits are not fully optimized or designed to test any theory.

Platinum metal  (Pto)
Survey, Peak-fits, BEs, FWHMs, and Peak Labels

→  Periodic Table   → Six (6) BE Tables
Survey Spectrum from Pto
Freshly exposed bulk, Flood gun is OFF, sample is conductive, Ag (3d5/2) FWHM = 1.3 eV
→  Periodic Table  → Six (6) BE Tables
Pt (4f) Spectrum from Pto – Raw
Fresh exposed bulk, Flood gun is ON, C (1s) BE = 284.4 eV, Ag FWHM = 0.75 eV		 Pt (4f) Spectrum from Pto – Peak-Fit
Freshly exposed bulk, Flood gun is ON, C (1s) BE = 284.4 eV, Ag FWHM = 0.75 eV
 
Pt (4f) Spectrum from Pto – Extended Range
Fresh exposed bulk, Flood gun is ON, C (1s) BE = 284.4 eV, Ag FWHM = 0.75 eV		 Pt (4f) Spectrum from Pto – Raw – Vertically Expanded
Freshly exposed bulk, Flood gun is ON, C (1s) BE = 284.4 eV, Ag FWHM = 0.75 eV
→  Periodic Table  → Six (6) BE Tables
O (1s) Spectrum 2 hrs after ion etching Pto – Peak-fit
Freshly exposed bulk, Flood gun is ON, C (1s) BE = 284.4 eV, Ag FWHM = 0.75 eV		 O (1s) Spectrum 12 hrs after ion etching Pto  – Peak-Fit
Freshly exposed bulk, Flood gun is ON, C (1s) BE = 284.4 eV, Ag FWHM = 0.75 eV
→  Periodic Table  → Six (6) BE Tables
C (1s) Spectrum 2 hrs after ion etching Pto – Peak-fit
Freshly exposed bulk, Flood gun is ON, C (1s) BE = 284.4 eV, Ag FWHM = 0.75 eV		 C (1s) Spectrum 12 hrs after ion etching Pto – Peak-Fit
Freshly exposed bulk, Flood gun is ON, C(1s) BE = 284.4 eV, Ag FWHM = 0.75 eV
→  Periodic Table  → Six (6) BE Tables
O (KLL) Auger Signals from Pto – Raw
Freshly exposed bulk, Flood gun is ON, C (1s) BE = 284.4 eV, Ag FWHM = 0.75 eV		 Valence Band Signals from Ptxx – Raw
Freshly exposed bulk, Flood gun is ON, C (1s) BE = 284.4 eV, Ag FWHM = 0.75 eV
 
Overlays
→  Periodic Table  → Six (6) BE Tables
Valence Band Spectra – Overlay of Pto and PtO2
Freshly exposed bulk, Flood gun is ON, C (1s) BE = 284.4 eV, Ag FWHM = 0.75 eV		 Pt (4f) Spectra – Overlay of Pto and PtO2
Freshly exposed bulk, Flood gun is ON, C (1s) BE = 284.4 eV, Ag FWHM = 0.75 eV

End-of-spectra

Price to purchase raw data sets:
Raw spectra – VAMAS ASCII format ($6)
Raw spectra – SDP binary format ($5)
SDP v9 – $145 (3 yr license)

 

 

Transmission Function Tests
 

December 2015 – Transmission Function of Thermo K-Alpha Plus
→  Periodic Table 
Survey Spectra of Ion Etched Copper (Sc), PEs = 50, 100, 150 and 200 eV
→  Periodic Table 
March 2016 – Transmission Function of Thermo K-Alpha Plus 
 
Survey Spectra of Ion Etched Copper (Sc), PEs = 100, 150 and 200 eV
→  Periodic Table  
August 2019 – Transmission Function of Thermo K-Alpha Plus
 
Survey Spectra of HOPG (C), PEs = 20, 50, 100 and 200 eV
→  Periodic Table  
January 2022 – Transmission Function of Thermo K-Alpha Plus
Survey Spectra of Ion Etched Copper (Sc), PEs = 100, 120, 140, 160, 180 and 200 eV

End-of-Transmission-Function-Tests

 

Six (6) Chemical State Tables of Pt (4f7/2) BEs

 

  • The XPS Library Spectra-Base
  • PHI Handbook
  • Thermo-Scientific Website
  • XPSfitting Website
  • Techdb Website
  • NIST Website

→  Periodic Table 

 

Notes of Caution when using Published BEs and BE Tables from Insulators and Conductors:

  • Accuracy of Published BEs
    • The accuracy depends on the calibration BEs used to calibrate the energy scale of the instrument.  Cu (2p3/2) BE can vary from 932.2 to 932.8 eV for old publications 
    • Different authors use different BEs for the C (1s) BE of the hydrocarbons found in adventitious carbon that appears on all materials and samples.  From 284.2 to 285.3 eV
    • The accuracy depends on when the authors last checked or adjusted their energy scale to produce the expected calibration BEs
  • Worldwide Differences in Energy Scale Calibrations
    • For various reasons authors still use older energy scale calibrations 
    • Some authors still adjust their energy scale so Cu (2p3/2) appears between 932.2 eV or 932.8 eV because this is what the maker taught them
    • This range causes BEs in the higher BE end to be larger than expected 
    • This variation increases significantly above 600 eV BE
  • Charge Compensation
    • Samples that behave as true insulators normally require the use of a charge neutralizer (electron flood gun with or without Ar+ ions) so that the measured chemical state spectra can be produced without peak-shape distortions or sloping tails on the low BE side of the peak envelop. 
    • Floating all samples (conductive, semi-conductive, and non-conductive) and always using the electron flood gun is considered to produce more reliable BEs and is recommended.
  • Charge Referencing Methods for Insulators
    • Charge referencing is a common method, but it can produce results that are less reliable.
    • When an electron flood gun is used, the BE scale will usually shift to lower BE values by 0.01 to 5.0 eV depending on your voltage setting. Normally, to correct for this flood gun induced shift, the BE of the hydrocarbon C (1s) peak maximum from adventitious carbon is used to correct for the charge induced shift.
    • The hydrocarbon peak is normally the largest peak at the lowest BE. 
    • Depending on your preference or training, the C (1s) BE assigned to this hydrocarbon peak varies from 284.8 to 285.0 eV.  Other BEs can be as low as 284.2 eV or as high as 285.3 eV
    • Native oxides that still show the pure metal can suffer differential charging that causes the C (1s) and the O (1s) and the Metal Oxide BE to be larger
    • When using the electron flood gun, the instrument operator should adjust the voltage and the XY position of the electron flood gun to produce peaks from a strong XPS signal (eg O (1s) or C (1s) having the most narrow FWHM and the lowest experimentally measured BE. 

→  Periodic Table 

Table #1

Pt (4f7/2) Chemical State BEs from:  “The XPS Library Spectra-Base”

C (1s) BE = 285.0 eV for TXL BEs
and C (1s) BE = 284.8 eV for NIST BEs

Element Atomic # Compound As-Measured by TXL or NIST Average BE Largest BE Hydrocarbon C (1s) BE  Source
Pt 78 Pt – element 71.0 eV 285.0 eV The XPS Library
Pt 78 Pt/Ni (N*7) 71.1 eV 71.2 eV 284.8 eV Avg BE – NIST
Pt 78 Pt3Ti (N*4) 71.4 eV 71.7 eV 284.8 eV Avg BE – NIST
Pt 78 Pt-Si (N*2) 72.5 eV 73 eV 284.8 eV Avg BE – NIST
Pt 78 Pt-(OH)2 (N*2) 72.6 eV 72.8 eV 284.8 eV Avg BE – NIST
Pt 78 K2PtCl4 (N*6) 72.9 eV 73.4 eV 284.8 eV Avg BE – NIST
Pt 78 K2PtI6 (N*2) 73.4 eV 284.8 eV Avg BE – NIST
Pt 78 Pt-Cl2 (N*1) 73.6 eV 284.8 eV Avg BE – NIST
Pt 78 PtO (N*5) 73.8 eV 74.6 eV 284.8 eV Avg BE – NIST
Pt 78 Pt-O 73.9 eV 285.0 eV The XPS Library
Pt 78 PtO2 (N*6) 74.1 eV 75.6 eV 284.8 eV Avg BE – NIST
Pt 78 PtO(OH)2 (N*1) 74.5 eV 284.8 eV Avg BE – NIST
Pt 78 Pt(OH)4 (N*1) 74.6 eV 284.8 eV Avg BE – NIST
Pt 78 K2Pt(OH)6 (N*2) 75.1 eV 284.8 eV Avg BE – NIST
Pt 78 Pt-O2 75.1 eV 285.0 eV The XPS Library
Pt 78 Pt-Cl4 (N*1) 75.5 eV 284.8 eV Avg BE – NIST
Pt 78 K2PtF6 (N*2) 77.6 eV 284.8 eV Avg BE – NIST

Charge Referencing Notes

  • (N*number) identifies the number of NIST BEs that were averaged to produce the BE in the middle column.
  • The XPS Library uses Binding Energy Scale Calibration with Cu (2p3/2) BE = 932.62 eV and Au (4f7/2) BE = 83.98 eV.  BE (eV) Uncertainty Range:  +/- 0.2 eV
  • Charge Referencing of insulators is defined such that the Adventitious Hydrocarbon C (1s) BE (eV) = 285.0 eV.  NIST uses C (1s) BE = 284.8 eV 
  • Note:   Ion etching removes adventitious carbon, implants Ar (+), changes conductivity of surface, and degrades chemistry of various chemical states.
  • Note:  Ion Etching changes BE of C (1s) hydrocarbon peak.
  • TXL – abbreviation for: “The XPS Library” (https://xpslibrary.com).  NIST:  National Institute for Science and Technology (in USA)

→  Periodic Table 

Table #2

Pt (4f7/2) Chemical State BEs from:  “PHI Handbook”

C (1s) BE = 284.8 eV

→  Periodic Table 

Copyright ©:  Ulvac-PHI

Table #3

Pt (4f7/2) Chemical State BEs from:  “Thermo-Scientific” Website

C (1s) BE = 284.8 eV

Chemical state Binding energy (eV), Pt (4f7/2)
Pt metal 71.0
PtO 72.4
PtO2 74.9

→  Periodic Table 

Copyright ©:  Thermo Scientific 

Table #4

Pt (4f7/2) Chemical State BEs from:  “XPSfitting” Website

Chemical State BE Table derived by Averaging BEs in the NIST XPS database of BEs
C (1s) BE = 284.8 eV

→  Periodic Table 

Copyright ©:  Mark Beisinger

Table #5

Pt (4f7/2) Chemical State BEs from:  “Techdb.podzone.net” Website

 

XPS Spectra – Chemical Shift / Binding Energy
C (1s) BE = 284.6 eV

XPS(X線光電子分光法)スペクトル 化学状態 化学シフト ケミカルシフト

Element Level Compound B.E.(eV) min max
Pt 4f7/2 Pt 71.1 ±0.1 71.0 ～ 71.2
Pt 4f7/2 Pt2Si 72.5 ±0.3 72.2 ～ 72.7
Pt 4f7/2 Pt(OH)2 72.6 ±0.3 72.3 ～ 72.8
Pt 4f7/2 I2Pt(Me3P)2cis 72.6 ±0.3 72.3 ～ 72.8
Pt 4f7/2 Cl2Pt(Ph3P)2cis 72.7 ±0.4 72.3 ～ 73.0
Pt 4f7/2 I2Pt(Me3P)2trans 72.8 ±0.3 72.5 ～ 73.0
Pt 4f7/2 PtSi 73.1 ±0.3 72.8 ～ 73.3
Pt 4f7/2 PtCl2 73.6 ±0.3 73.3 ～ 73.8
Pt 4f7/2 Oxides 74.4 ±0.6 73.8 ～ 75.0
Pt 4f7/2 (IV)Halides 75.5 ±2.1 73.4 ～ 77.6
Pt 4f7/2 PtCl4 75.6 ±0.3 75.3 ～ 75.8

 

→  Periodic Table 

 


Histograms of NIST BEs for Pt (4f7/2) BEs

Important Note:  NIST Database defines Adventitious Hydrocarbon C (1s) BE = 284.8 eV for all insulators.

Histogram indicates:  71.1 eV for Pto based on 31 literature BEs Histogram indicates:  74.9 eV for PtO based on 6 literature BEs

Histogram indicates:  74.8 eV for PtO2 based on 6 literature BEs

Table #6


NIST Database of Pt (4f7/2) Binding Energies

NIST Standard Reference Database 20, Version 4.1

Data compiled and evaluated
by
Alexander V. Naumkin, Anna Kraut-Vass, Stephen W. Gaarenstroom, and Cedric J. Powell
©2012 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved.

Important Note:  NIST Database defines Adventitious Hydrocarbon C (1s) BE = 284.8 eV for all insulators.

 

Element Spectral Line Formula Energy (eV) Reference
Pt 4f7/2 Ag98.9Pt1.1 70.20  Click
Pt 4f7/2 Ag95.8Pt4.2 70.40  Click
Pt 4f7/2 Cu/Pt 70.60  Click
Pt 4f7/2 Cu/Pt 70.60  Click
Pt 4f7/2 Pt 70.61  Click
Pt 4f7/2 CO/Cu/Pt 70.63  Click
Pt 4f7/2 Pt/Cu 70.64  Click
Pt 4f7/2 Pt/CeO2+TiO2 (80-20) 70.70  Click
Pt 4f7/2 Pt 70.72  Click
Pt 4f7/2 CO/Pt 70.72  Click
Pt 4f7/2 O/Pt 70.72  Click
Pt 4f7/2 Pt/CCH3 70.72  Click
Pt 4f7/2 Pt 70.73  Click
Pt 4f7/2 Sn/Pt 70.73  Click
Pt 4f7/2 Sn/Pt 70.73  Click
Pt 4f7/2 Pt 70.74  Click
Pt 4f7/2 Co/Pt 70.74  Click
Pt 4f7/2 H2/Sn/Pt 70.76  Click
Pt 4f7/2 H2/Sn/Pt 70.76  Click
Pt 4f7/2 Pt/Co/Pt 70.81  Click
Pt 4f7/2 Pt 70.83  Click
Pt 4f7/2 Pt/CO 70.83  Click
Pt 4f7/2 Co75Pt25 70.83  Click
Pt 4f7/2 Pt/K 70.84  Click
Pt 4f7/2 Pt 70.87  Click
Pt 4f7/2 Pt 70.90  Click
Pt 4f7/2 Pt 70.90  Click
Pt 4f7/2 Pt 70.90  Click
Pt 4f7/2 Ag5.3Pt94.7 70.90  Click
Pt 4f7/2 CO/Cu/Pt 70.95  Click
Pt 4f7/2 Cu/Pt 70.97  Click
Pt 4f7/2 Cu/Pt 70.97  Click
Pt 4f7/2 Pt 70.99  Click
Pt 4f7/2 Pt 71.00  Click
Pt 4f7/2 Pt 71.00  Click
Pt 4f7/2 Pt/Al2O3 71.00  Click
Pt 4f7/2 Pt(P(C6H5)3)2((CH3)2NC6H4NO) 71.00  Click
Pt 4f7/2 O2/Pt 71.00  Click
Pt 4f7/2 Pt/Cu 71.00  Click
Pt 4f7/2 Pt 71.07  Click
Pt 4f7/2 Pt 71.07  Click
Pt 4f7/2 Pt 71.08  Click
Pt 4f7/2 O2/Pt 71.08  Click
Pt 4f7/2 Co/Pt 71.08  Click
Pt 4f7/2 Pt 71.09  Click
Pt 4f7/2 Pt 71.09  Click
Pt 4f7/2 O2/Pt 71.09  Click
Pt 4f7/2 Pt 71.10  Click
Pt 4f7/2 Pt 71.10  Click
Pt 4f7/2 Pt 71.10  Click
Pt 4f7/2 Pt 71.10  Click
Pt 4f7/2 Pt 71.10  Click
Pt 4f7/2 Pt 71.10  Click
Pt 4f7/2 Pt 71.10  Click
Pt 4f7/2 Pt 71.10  Click
Pt 4f7/2 Pt90Rh10 71.10  Click
Pt 4f7/2 Pt90Rh10 71.10  Click
Pt 4f7/2 Pt/Ni 71.10  Click
Pt 4f7/2 Pt0.042C 71.10  Click
Pt 4f7/2 Pt0.042C 71.10  Click
Pt 4f7/2 Pt0.007C 71.10  Click
Pt 4f7/2 Pt0.007C 71.10  Click
Pt 4f7/2 Pt2.830C 71.10  Click
Pt 4f7/2 Pt2.830C 71.10  Click
Pt 4f7/2 Pt 71.12  Click
Pt 4f7/2 CO/Pt 71.12  Click
Pt 4f7/2 CO/Pt 71.12  Click
Pt 4f7/2 O/Pt 71.12  Click
Pt 4f7/2 Pt/CCH3 71.12  Click
Pt 4f7/2 Pt0.013C 71.12  Click
Pt 4f7/2 Pt0.013C 71.12  Click
Pt 4f7/2 Pt0.012C 71.12  Click
Pt 4f7/2 Pt0.012C 71.12  Click
Pt 4f7/2 Pt 71.13  Click
Pt 4f7/2 Pt 71.13  Click
Pt 4f7/2 Co/Pt 71.13  Click
Pt 4f7/2 Co/Pt 71.13  Click
Pt 4f7/2 Pt/Co/Pt 71.13  Click
Pt 4f7/2 Pt/Co/Pt 71.13  Click
Pt 4f7/2 Pt 71.14  Click
Pt 4f7/2 Pt0.011C 71.14  Click
Pt 4f7/2 Pt0.011C 71.14  Click
Pt 4f7/2 Pt/Ni 71.15  Click
Pt 4f7/2 Pt/Ni 71.15  Click
Pt 4f7/2 Pt 71.20  Click
Pt 4f7/2 Pt 71.20  Click
Pt 4f7/2 Pt 71.20  Click
Pt 4f7/2 Pt 71.20  Click
Pt 4f7/2 Pt 71.20  Click
Pt 4f7/2 Pt90Rh10 71.20  Click
Pt 4f7/2 Pt/Ni 71.20  Click
Pt 4f7/2 Pt/Ni 71.20  Click
Pt 4f7/2 Pt/Ni 71.20  Click
Pt 4f7/2 Ag98.9Pt1.1 71.20  Click
Pt 4f7/2 Pt/Si 71.22  Click
Pt 4f7/2 Pt/Ni 71.25  Click
Pt 4f7/2 [Pt(CH3)2(P(C6H5)3)2] 71.30  Click
Pt 4f7/2 Pt 71.30  Click
Pt 4f7/2 Pt 71.30  Click
Pt 4f7/2 Pt 71.30  Click
Pt 4f7/2 Pt 71.30  Click
Pt 4f7/2 Pt 71.30  Click
Pt 4f7/2 Pt3Ti 71.30  Click
Pt 4f7/2 Pt/CeO2+TiO2 (20-80) 71.30  Click
Pt 4f7/2 O2/Pt3Ti 71.30  Click
Pt 4f7/2 O2/Pt3Ti 71.30  Click
Pt 4f7/2 O2/Pt3Ti 71.30  Click
Pt 4f7/2 Pt84Re16 71.31  Click
Pt 4f7/2 O/Pt 71.34  Click
Pt 4f7/2 Co75Pt25 71.36  Click
Pt 4f7/2 Co75Pt25 71.38  Click
Pt 4f7/2 [Pt(P(C6H5)3)3] 71.40  Click
Pt 4f7/2 [Pt(P(C6H5)3)3] 71.40  Click
Pt 4f7/2 [Pt((C6H5)3P)4] 71.40  Click
Pt 4f7/2 Pt3Ti 71.40  Click
Pt 4f7/2 O2/Pt3Ti 71.40  Click
Pt 4f7/2 Pt(P(C6H5)3)4 71.40  Click
Pt 4f7/2 [(C6H5)3P]3Pt 71.40  Click
Pt 4f7/2 Co/Pt 71.40  Click
Pt 4f7/2 Pt83Re17 71.44  Click
Pt 4f7/2 Pt/CCH3 71.48  Click
Pt 4f7/2 Pt/CeO2+TiO2 (80-20) 71.50  Click
Pt 4f7/2 Pt(P(C6H5)3)4 71.50  Click
Pt 4f7/2 [(Pt(P(C6H5)3)2S)2PtCl2] 71.50  Click
Pt 4f7/2 Pt/Co/Pt 71.56  Click
Pt 4f7/2 Pt/Co/Pt 71.56  Click
Pt 4f7/2 H2/Sn/Pt 71.57  Click
Pt 4f7/2 H2/Sn/Pt 71.57  Click
Pt 4f7/2 Pt3Ti 71.60  Click
Pt 4f7/2 Pt/CeO2+TiO2 (20-80) 71.60  Click
Pt 4f7/2 Re/Pt 71.60  Click
Pt 4f7/2 Co/Pt 71.60  Click
Pt 4f7/2 Pt73Re27 71.63  Click
Pt 4f7/2 Pt3Ti 71.65  Click
Pt 4f7/2 CO/Pt3Ti 71.65  Click
Pt 4f7/2 Pt3Ti 71.70  Click
Pt 4f7/2 Pt4H3Na45(AlO2)56(SiO2)136 71.70  Click
Pt 4f7/2 [Pt2(SP(C6H5)2)2(P(C6H5)3)2] 71.80  Click
Pt 4f7/2 [Pt(SP(C6H5)3)(P(C6H5)2)] 71.80  Click
Pt 4f7/2 Cl2(C5H5N)(CH2C5H5N)Pt 71.80  Click
Pt 4f7/2 [Pt(AuP(C6H5)3)8](NO3)2 71.80  Click
Pt 4f7/2 Pt53Re47 71.84  Click
Pt 4f7/2 K2[Pt(SCN)4] 71.90  Click
Pt 4f7/2 (C6H4S4)2(C6H4S4)[Pt(S2C2O2)2] 71.90  Click
Pt 4f7/2 [P(C6H5)3Pt(AuP(C6H5)3)6](NO3)2 71.90  Click
Pt 4f7/2 [P(C6H5)3HPt(AuP(C6H5)3)7](NO3)2 71.90  Click
Pt 4f7/2 Pt3(CO)Cl((C6H5)2PCH2P(C6H5)2)3[PF6] 71.90  Click
Pt 4f7/2 Pt4H7Na41(AlO2)56(SiO2)136 71.90  Click
Pt 4f7/2 Pt4H11Na37(AlO2)56(SiO2)136 71.90  Click
Pt 4f7/2 Pt39Re61 71.98  Click
Pt 4f7/2 [Pt3(CO)3(C6H11PH2)3] 72.00  Click
Pt 4f7/2 N(C2H5)4[Pt(S2C2O2)2] 72.00  Click
Pt 4f7/2 [P(C6H5)3Pt(AuP(C6H5)3)6(HgNO3)]NO3 72.00  Click
Pt 4f7/2 [IP(C6H5)3Pt(AuP(C6H5)3)4]BF4 72.00  Click
Pt 4f7/2 [(P(C6H5)3)2Pt(AuP(C6H5)3)3]PF6 72.00  Click
Pt 4f7/2 Pt4H20Na28(AlO2)56(SiO2)136 72.00  Click
Pt 4f7/2 (C6H4S4)2[Pt(S2C2O2)2] 72.05  Click
Pt 4f7/2 [PtCl2(P(C4H9)3)2] 72.10  Click
Pt 4f7/2 [N(C2H5)4]2[Pt(B10H12)2] 72.10  Click
Pt 4f7/2 ((CH3)2(CH3(CH2)17)2N)Pt(Cl)6/SiO2 72.10  Click
Pt 4f7/2 [(Pt(P(C6H5)3)2S)2] 72.10  Click
Pt 4f7/2 CO/Pt 72.13  Click
Pt 4f7/2 [Pt(CH3)2(P(C2H5)3)2] 72.20  Click
Pt 4f7/2 [Pt(C2H4)(P(C6H5)3)2] 72.20  Click
Pt 4f7/2 [Pt2Cl2((C6H5)2PCH2P(C6H5)2)2] 72.20  Click
Pt 4f7/2 [PtCl2(CH3SCH2CH2CH(NH2)COOH)] 72.20  Click
Pt 4f7/2 [Pt((C6H5)2PCH2P(C6H5)2)(CH3)2] 72.20  Click
Pt 4f7/2 [N(C2H5)4][Pt((C6H5)C(S)C(S)(C6H5))2] 72.20  Click
Pt 4f7/2 [(C2H5)3P]2Pt(CH3)2 72.20  Click
Pt 4f7/2 [Pt((C2H5)2NC(S)S)2] 72.30  Click
Pt 4f7/2 [PtCl2(P(C6H5)3)2] 72.30  Click
Pt 4f7/2 cis-[PtCl2(P(C6H5)3)2] 72.30  Click
Pt 4f7/2 PtOSn 72.30  Click
Pt 4f7/2 Pt3(CO)(SnF3)((C6H5)2PCH2P(C6H5)2)3[PF6] 72.30  Click
Pt 4f7/2 [P(C6H5)3COPt(AuP(C6H5)3)5]Cl 72.30  Click
Pt 4f7/2 [P(C6H5)3Pt(AuP(C6H5)3)5(HgNO3)2]NO3 72.30  Click
Pt 4f7/2 [P(C6H5)3CNPt(AuP(C6H5)3)6]NO3 72.30  Click
Pt 4f7/2 [PtBr2((CH3NCH)NHNH(CHNCH3))] 72.40  Click
Pt 4f7/2 [Pt(C2H2)(P(C6H5)3)2] 72.40  Click
Pt 4f7/2 (NH4)2[PtCl4] 72.40  Click
Pt 4f7/2 PtO 72.40  Click
Pt 4f7/2 [AuPt3(CO)3(C6H11PH2)4].PF6 72.40  Click
Pt 4f7/2 [(Pt(P(C6H5)3)2S)2PtCl2] 72.40  Click
Pt 4f7/2 [PtI2(P(C2H5)3)2] 72.50  Click
Pt 4f7/2 [Pt(H2NC(O)NHC(O)NH2)2]Cl2 72.50  Click
Pt 4f7/2 [Pt((C6H5)CSSC(C6H5))2] 72.50  Click
Pt 4f7/2 [Pt(C2H4)(P(C6H5)3)2] 72.50  Click
Pt 4f7/2 [Pt(C6H5)2(P(C2H5)3)2] 72.50  Click
Pt 4f7/2 Pt2Si 72.50  Click
Pt 4f7/2 [(C2H5)3P]2Pt(C6H5)2 72.50  Click
Pt 4f7/2 Pt3(SnF3)2((C6H5)2PCH2P(C6H5)2)3[PF6] 72.50  Click
Pt 4f7/2 Pt/Si 72.50  Click
Pt 4f7/2 [(CO)3(P(C6H5)3)4Pt3(AuP(C6H5)3)]NO3 72.50  Click
Pt 4f7/2 [Pt3(Re(CO)3))((C6H5)2PCH2P(C6H5)2)3][PF6] 72.50  Click
Pt 4f7/2 [Pt3(Re(CO)3))O((C6H5)2PCH2P(C6H5)2)3][PF6] 72.50  Click
Pt 4f7/2 PtS 72.55  Click
Pt 4f7/2 [PtI2(P(CH3)3)2] 72.60  Click
Pt 4f7/2 [PtClCH3(P(C2H5)3)2] 72.60  Click
Pt 4f7/2 K2[PtBr4] 72.60  Click
Pt 4f7/2 K2[PtBr4] 72.60  Click
Pt 4f7/2 Pt(OH)2 72.60  Click
Pt 4f7/2 [PtClH(P(C2H5)3)2] 72.60  Click
Pt 4f7/2 [(C2H5)3P]2PtHCl 72.60  Click
Pt 4f7/2 [(C2H5)3P]2PtCH3Cl 72.60  Click
Pt 4f7/2 [(C6H5)2PCH2CH2P(C6H5)2Pt(AuP(C6H5)3)4](PF6)2 72.60  Click
Pt 4f7/2 [CNPt(AuP(C6H5)3)8AuCN]NO3 72.60  Click
Pt 4f7/2 [CN(CH3)2C6H3Pt(AuP(C6H5)3)8](NO3)2 72.60  Click
Pt 4f7/2 [Pt2(P(C6H5)3)4SSCH3]I 72.60  Click
Pt 4f7/2 [(Pt2(P(C6H5)3)4S2Cu)2(mu-dppf)][PF6]2 72.60  Click
Pt 4f7/2 ((CH3)2(CH3(CH2)17)2N)Pt(Cl)6/SiO2 72.60  Click
Pt 4f7/2 [(Pt(P(C6H5)3)2S)2Au(P(C6H5)3)]PF6 72.60  Click
Pt 4f7/2 (C8H12)PtCl2 72.65  Click
Pt 4f7/2 [PtI2(P(CH3)3)2] 72.70  Click
Pt 4f7/2 [PtCl2(P(C2H5)3)2] 72.70  Click
Pt 4f7/2 [PtCl2(O2)(C10H8N2)] 72.70  Click
Pt 4f7/2 Pt3(CO)((C6H5)2PCH2P(C6H5)2)3[PF6]2 72.70  Click
Pt 4f7/2 [Pt2(P(C6H5)3)4SSCHCl2]PF6 72.70  Click
Pt 4f7/2 [(Pt2(P(C6H5)3)4S2Pd)2Cl2][PF6]2 72.70  Click
Pt 4f7/2 [(Pt2(P(C6H5)3)4S2)2Ag2][NO3]2 72.70  Click
Pt 4f7/2 [Pt(C2F4)(P(C6H5)3)2] 72.80  Click
Pt 4f7/2 [Pt(C2H4)(P(C6H5)3)2] 72.80  Click
Pt 4f7/2 [Pt2S2(P(C6H5)3)4] 72.80  Click
Pt 4f7/2 [Pt(-C-6H5S)2] 72.80  Click
Pt 4f7/2 Pt(OH)2 72.80  Click
Pt 4f7/2 Pt/CeO2+TiO2 (20-80) 72.80  Click
Pt 4f7/2 [(Pt(P(C6H5)3)2S)2Hg(C6H5)2PCH2CH2P(C6H5)2)][PF6]2 72.80  Click
Pt 4f7/2 [(Pt2(P(C6H5)3)4S2)2Hg][PF6]2 72.80  Click
Pt 4f7/2 [Pt2(P(C6H5)3)4SSCH2Cl]Cl 72.80  Click
Pt 4f7/2 Pt/Si 72.82  Click
Pt 4f7/2 K2PtCl4 72.90  Click
Pt 4f7/2 K2PtCl4 72.90  Click
Pt 4f7/2 [Pt2(NH3)4(C5H4ON)2]2(NO3)5 72.90  Click
Pt 4f7/2 [PtCl2(P(C6H5)3)2] 72.90  Click
Pt 4f7/2 [Pt3(ReO3)((C6H5)2PCH2P(C6H5)2)3][PF6]CH2Cl2 72.90  Click
Pt 4f7/2 [Pt3(Re(CO)3))O3((C6H5)2PCH2P(C6H5)2)3][PF6] 72.90  Click
Pt 4f7/2 [Pt2(P(C6H5)3)4SSCH2C6H5]PF6 72.90  Click
Pt 4f7/2 [Pt3(Re(CO)3))O2((C6H5)2PCH2P(C6H5)2)3][PF6]OC2H5 72.90  Click
Pt 4f7/2 [PtB10H12(P(C6H5)3)2] 73.00  Click
Pt 4f7/2 [PtCl(C2Cl3)(P(C6H5)3)2] 73.00  Click
Pt 4f7/2 [Pt(C(HNCH3)2)4(PF6)2] 73.00  Click
Pt 4f7/2 K2PtCl4 73.00  Click
Pt 4f7/2 K2PtCl4 73.00  Click
Pt 4f7/2 [PtBr4(C4H10N4)] 73.00  Click
Pt 4f7/2 [PtCl2(H2NC2H4NH2)2] 73.00  Click
Pt 4f7/2 [Pt(O2)((C6H5)3P)2] 73.00  Click
Pt 4f7/2 [PtCl2(P(C6H5)3)2] 73.00  Click
Pt 4f7/2 cis-[PtCl2(P(C6H5)3)2] 73.00  Click
Pt 4f7/2 [Pt(H2NC2H4NH2)2][PtCl2(H2NC2H4NH2)2](ClO4)2 73.00  Click
Pt 4f7/2 [N(C2H5)4]3[Pt(SnCl3)5] 73.00  Click
Pt 4f7/2 PtSi 73.00  Click
Pt 4f7/2 [(Pt(P(C6H5)3)2S)2Ni(C6H5)2PCH2CH2P(C6H5)2)][PF6]2 73.00  Click
Pt 4f7/2 (-Pt((C4H9)3P)2-C&=C-C6H4-C6H4-C&=C-)n 73.00  Click
Pt 4f7/2 [PtCl2(P(C2H5)3)2] 73.10  Click
Pt 4f7/2 [PtCl4((CH3NCH)NHNH(CHNCH3))] 73.10  Click
Pt 4f7/2 [PtCl2(CH2(P(C6H5)2)2)] 73.10  Click
Pt 4f7/2 [PtCl2(NH(C6H5)NHC(S)SCH3)2] 73.10  Click
Pt 4f7/2 K2PtCl4 73.10  Click
Pt 4f7/2 [N(CH3)4]2[Pt(SnCl3)5] 73.10  Click
Pt 4f7/2 [PtCl2(P(C6H5)3)2] 73.10  Click
Pt 4f7/2 [Pt(NH3)2]Cl2 73.10  Click
Pt 4f7/2 Pt/CeO2+TiO2 (80-20) 73.10  Click
Pt 4f7/2 [Pt(NH2(CH2)2NH(CH2)2NH2)NO3]NO3 73.10  Click
Pt 4f7/2 Pt((C4H9)3P)2Cl2 73.10  Click
Pt 4f7/2 [PtCl2(C6H5)2PCH2CH2P(C6H5)2] 73.10  Click
Pt 4f7/2 [Pt(SCN)4(P(C6H5)4)2] 73.20  Click
Pt 4f7/2 [N(CH3)4]2[PtCl2(SnCl3)2] 73.20  Click
Pt 4f7/2 [PtCl2(P(C6H5)3)2] 73.20  Click
Pt 4f7/2 cis-[PtCl2(P(C6H5)3)2] 73.20  Click
Pt 4f7/2 [Pt(NH3)2]Cl2 73.20  Click
Pt 4f7/2 [Pt(NH3)2]Cl2 73.20  Click
Pt 4f7/2 K2PtCl4 73.20  Click
Pt 4f7/2 Pt(C32H16N8) 73.20  Click
Pt 4f7/2 Pt(C32H16N8)(AsF6)x 73.20  Click
Pt 4f7/2 Pt(C32H16N8)(AsF6)x 73.20  Click
Pt 4f7/2 Pt(C32H16N8)(ClO4)0.5 73.20  Click
Pt 4f7/2 C32H16N8Pt(AsF6)0.5 73.20  Click
Pt 4f7/2 C32H16N8Pt(ClO4)0.5 73.20  Click
Pt 4f7/2 C32H16N8Pt 73.20  Click
Pt 4f7/2 PtCl2((C6H5)2PCH2P(C6H5)2) 73.20  Click
Pt 4f7/2 PtCl2 73.20  Click
Pt 4f7/2 [Pt3(ReO3)O3((C6H5)2PCH2P(C6H5)2)3][PF6] 73.20  Click
Pt 4f7/2 [PtCl2(C3NO(CH3)2(NH2))2] 73.30  Click
Pt 4f7/2 [Pt(NH2NH2ClC(S)SCH3)2] 73.30  Click
Pt 4f7/2 [PtBr2((CH3)C3HNO(C6H5))2] 73.30  Click
Pt 4f7/2 [Pt(NH2(CH2)2NH(CH2)2NH2)Cl]Cl 73.30  Click
Pt 4f7/2 [Pt(B10H12)(P(C2H5)3)2] 73.40  Click
Pt 4f7/2 [Pt2(CNCH3)6(PF6)2] 73.40  Click
Pt 4f7/2 K2PtCl4 73.40  Click
Pt 4f7/2 K2PtCl4 73.40  Click
Pt 4f7/2 Pt(NH3)4Br2 73.40  Click
Pt 4f7/2 Pt(NH3)4Br2 73.40  Click
Pt 4f7/2 Pt(NH3)4Cl2 73.40  Click
Pt 4f7/2 Pt(NH3)4Cl2 73.40  Click
Pt 4f7/2 [Pt(H2NC2H4NH2)2][PtI2(H2NC2H4NH2)2](ClO4)2 73.40  Click
Pt 4f7/2 K2PtI6 73.40  Click
Pt 4f7/2 K2PtI6 73.40  Click
Pt 4f7/2 K4[Pt2(P2O5H2)4I].nH2O 73.40  Click
Pt 4f7/2 PtNH3Cl2 73.40  Click
Pt 4f7/2 [Pt2(NCCH3)6].(BF4)2 73.50  Click
Pt 4f7/2 [PtCl2((CH3)C3HNO(C6H5))2] 73.50  Click
Pt 4f7/2 [PtBr2(C3HNO(C6H5)2)2] 73.50  Click
Pt 4f7/2 K4[Pt2(P2O5H2)4].3H2O 73.50  Click
Pt 4f7/2 PtCl2 73.60  Click
Pt 4f7/2 [Pt(CH3CONH)2].H2O 73.60  Click
Pt 4f7/2 [Pt(CH3CONH)2].H2O 73.60  Click
Pt 4f7/2 [PtCl2(C3HNO(C6H5)2)2] 73.60  Click
Pt 4f7/2 K4[Pt2(P2O5H2)4Cl].3H2O 73.60  Click
Pt 4f7/2 [Pt(CN)2(P(C2H5)3)2] 73.70  Click
Pt 4f7/2 [Pt(NH3)2(NO2)2] 73.70  Click
Pt 4f7/2 [Pt(NH3)2(NO2)2] 73.70  Click
Pt 4f7/2 Pt/CeO2+TiO2 (20-80) 73.70  Click
Pt 4f7/2 [Pt(S(NH)C6H4)2] 73.70  Click
Pt 4f7/2 [(C2H5)3P]2Pt(CN)2 73.70  Click
Pt 4f7/2 K4[Pt2(P2O5H2)4Br].3H2O 73.70  Click
Pt 4f7/2 [Pt(C2H3O2)2] 73.80  Click
Pt 4f7/2 PtO 73.80  Click
Pt 4f7/2 K2Pt(CN)4 73.80  Click
Pt 4f7/2 [PtCl2(C8H12)] 73.90  Click
Pt 4f7/2 Pt/CeO2+TiO2 (20-80) 73.90  Click
Pt 4f7/2 [PtCl4(C2H5NH2)4] 74.10  Click
Pt 4f7/2 [PtCl2(C8H12)] 74.10  Click
Pt 4f7/2 K2[Pt(NO2)4] 74.10  Click
Pt 4f7/2 K2[Pt(NO2)4] 74.10  Click
Pt 4f7/2 PtO2 74.10  Click
Pt 4f7/2 PtS2 74.16  Click
Pt 4f7/2 K2PtCl4 74.20  Click
Pt 4f7/2 K2[Pt(CN)4].3H2O 74.20  Click
Pt 4f7/2 PtO 74.20  Click
Pt 4f7/2 PtO 74.20  Click
Pt 4f7/2 [Pt(H2NC2H4NH2)2][PtI2(H2NC2H4NH2)2](ClO4)2 74.30  Click
Pt 4f7/2 [PtCl6(-NHC(CH3)C(OH)C(CH2OH)C(CH2OH)CH-)2] 74.40  Click
Pt 4f7/2 [Pt(NH3)2(NO2)2] 74.40  Click
Pt 4f7/2 Pt(OH)2O 74.50  Click
Pt 4f7/2 Pt(SO4)2.nH2O 74.60  Click
Pt 4f7/2 [PtI2(CH3C(O)NH)4] 74.60  Click
Pt 4f7/2 Pt(OH)4 74.60  Click
Pt 4f7/2 K2PtBr6 74.60  Click
Pt 4f7/2 K2PtBr6 74.60  Click
Pt 4f7/2 PtO2 74.60  Click
Pt 4f7/2 PtO 74.60  Click
Pt 4f7/2 PtO 74.60  Click
Pt 4f7/2 O2/Pt3Ti 74.60  Click
Pt 4f7/2 [Pt(NH2(CH2)2NH(CH2)2NH2)CN]I 74.60  Click
Pt 4f7/2 [Pt(NH2(CH2)2NH(CH2)2NH2)NO2]I 74.60  Click
Pt 4f7/2 [Pt(NH2(CH2)2NH(CH2)2NH2)I]I 74.70  Click
Pt 4f7/2 [PtCl2(CH3C(O)NH)4] 74.80  Click
Pt 4f7/2 [Pt2Br2(CH3C(O)NH)4] 74.90  Click
Pt 4f7/2 PtO2 74.90  Click
Pt 4f7/2 PtO2 74.90  Click
Pt 4f7/2 [Pt(CH3CN)4(PF6)2] 75.00  Click
Pt 4f7/2 [Pt2(NO3)2(CH3C(O)NH)4] 75.00  Click
Pt 4f7/2 [Pt(NO3)2(CH3C(O)NH)4] 75.00  Click
Pt 4f7/2 [Pt(NO2)2(CH3C(O)NH)4] 75.00  Click
Pt 4f7/2 [Pt(H2NC2H4NH2)2][PtCl2(H2NC2H4NH2)2](ClO4)2 75.00  Click
Pt 4f7/2 PtO2 75.00  Click
Pt 4f7/2 K2Pt(OH)6 75.10  Click
Pt 4f7/2 K2Pt(OH)6 75.10  Click
Pt 4f7/2 [PtI2((NH2)2CHCH3)2][Pd((NH2)2CHCH3)2](ClO4)4 75.20  Click
Pt 4f7/2 K2[PtCl6] 75.20  Click
Pt 4f7/2 [PtCl4(P(C2H5)3)2] 75.30  Click
Pt 4f7/2 [PtCl2(H2NCH2CH2NH2)2]Cl2 75.30  Click
Pt 4f7/2 [PtBr2((NH2)2CHCH3)2][Ni((NH2)2CHCH3)2](ClO4)4 75.40  Click
Pt 4f7/2 K2[PtCl6] 75.40  Click
Pt 4f7/2 [Pd(H2NC2H4NH2)2][PtBr2(H2NC2H4NH2)2](ClO4)4 75.40  Click
Pt 4f7/2 K[PtCl6] 75.40  Click
Pt 4f7/2 PtO2 75.40  Click
Pt 4f7/2 [Pt2(C2H3O2)6] 75.50  Click
Pt 4f7/2 PtCl4 75.50  Click
Pt 4f7/2 K2[PtCl6] 75.50  Click
Pt 4f7/2 K2[PtCl6] 75.50  Click
Pt 4f7/2 K2[PtCl6] 75.50  Click
Pt 4f7/2 [PtCl2((NH2)2CHCH3)2][Ni((NH2)2CHCH3)2](ClO4)4 75.60  Click
Pt 4f7/2 [PtCl2((NH2)2CHCH3)2][Pd((NH2)2CHCH3)2](ClO4)4 75.60  Click
Pt 4f7/2 [PtCl2(H2NCH2CH2NH2)2]Cl2 75.60  Click
Pt 4f7/2 K2[PtCl6] 75.60  Click
Pt 4f7/2 PtO2 75.60  Click
Pt 4f7/2 [PtClH(P(C2H5)3)2] 75.70  Click
Pt 4f7/2 K2PtCl6 75.70  Click
Pt 4f7/2 [PtCl4(P(C2H5)3)2] 75.90  Click
Pt 4f7/2 [PtCl4(P(C2H5)3)2] 75.90  Click
Pt 4f7/2 [PtHCl(P(C6H5)3)2] 75.90  Click
Pt 4f7/2 K2[Pt(NO2)6] 75.90  Click
Pt 4f7/2 K2[Pt(NO2)6] 75.90  Click
Pt 4f7/2 [(C2H5)3P]2PtCl4 75.90  Click
Pt 4f7/2 PtCl4 75.90  Click
Pt 4f7/2 K2[Pt(NO2)3(NO3)3] 76.00  Click
Pt 4f7/2 [PtCl2(P(C2H5)3)2] 76.20  Click
Pt 4f7/2 [PtH(SnCl3)(P(C2H5)3)2] 76.20  Click
Pt 4f7/2 [Pt(NH3)6]Cl4 76.30  Click
Pt 4f7/2 [Pt(NH3)6]Cl4 76.30  Click
Pt 4f7/2 [PtCl2(P(C6H5)3)2] 76.30  Click
Pt 4f7/2 [PtCl2(P(C2H5)3)2] 76.40  Click
Pt 4f7/2 [PtCl2(C2H5NH2)4].4H2O 76.40  Click
Pt 4f7/2 K2[PtCl2(CN)4].3H2O 76.60  Click
Pt 4f7/2 K2PtF6 77.60  Click
Pt 4f7/2 K2PtF6 77.60  Click

 


Statistical Analysis of Binding Energies in NIST XPS Database of BEs