Sio | n-Sio | p-Sio | SiC | SiO | SiO2 | SiO2-nH2O | Si3N4 | SiGex | SiON |
Al2SiO5 | Al2Si2O13 | Be2SiO4 | CaTiSiO5 | K2SiO3 | MgSiO3 | Mg3Si4O10(OH)2 | Na2Si3O7 | ZrSiO4 | Silicic Acid |
PDMS | PMPS | Soda-lime Glass | NIST 610 | NIST 612 | NIST 614 | Ba-Borosilicate | Silica Gel | Colloidal SiO2 | Basic |
XPS Spectra
Silicon (Si) Compounds
The XPS Spectra section provides raw and processed survey spectra, chemical state spectra, BE values, FWHM values, and overlays of key spectra.
Atom% values from surveys are based on sample, as received, and Scofield cross-sections. Atom% values are corrected for IMFP and PE.
Peak-fits are guides for practical, real-world applications. Peak-fits are not fully optimized or designed to test any theory.
NIST SRM 614 – Trace Elements in Glass
Survey, Peak-fits, BEs, FWHMs, and Peak Labels
→ Periodic Table | → Six (6) BE Tables |
Survey Spectrum from NIST SRM 614 Freshly exposed bulk, Flood gun is ON, C (1s) BE = 285.0 eV, Ag (3d5/2) FWHM = 1.3 eV |
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→ Periodic Table | → Six (6) BE Tables |
Si (2p) Spectrum from NIST SRM 614 – Raw Fresh exposed bulk, Flood gun is ON, C (1s) BE = 285.0 eV, Ag FWHM = 0.75 eV |
Si (2p) Spectrum from NIST SRM 614 – Peak-Fit Freshly exposed bulk, Flood gun is ON, C (1s) BE = 285.0 eV, Ag FWHM = 0.75 eV |
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→ Periodic Table | → Six (6) BE Tables |
O (1s) Spectrum from NIST SRM 614 – Raw Freshly exposed bulk, Flood gun is ON, C (1s) BE = 285.0 eV, Ag FWHM = 0.75 eV |
O (1s) Spectrum from NIST SRM 614 – Peak-fit Freshly exposed bulk, Flood gun is ON, C (1s) BE = 285.0 eV, Ag FWHM = 0.75 eV |
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→ Periodic Table | → Six (6) BE Tables |
P (2p) Spectrum from NIST SRM 614 – Raw – Extended Freshly exposed bulk, Flood gun is ON, C (1s) BE = 285.0 eV, Ag FWHM = 0.75 eV |
P (2p) Spectrum from NIST SRM 614 – Raw – Expanded Freshly exposed bulk, Flood gun is ON, C (1s) BE = 285.0 eV, Ag FWHM = 0.75 eV |
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→ Periodic Table | → Six (6) BE Tables |
C (1s) Spectrum from NIST SRM 614– Peak-fit – As measured Freshly exposed bulk, Flood gun is ON, C (1s) BE = 284.17 eV, Ag FWHM = 0.75 eV |
C (1s) Spectrum from NIST SRM 614 – Peak-Fit – Corrected Freshly exposed bulk, Flood gun is ON, C (1s) BE = 285.0 eV, Ag FWHM = 0.75 eV |
→ Periodic Table | → Six (6) BE Tables |
Mg (1s) Spectrum from NIST SRM 614 – Raw Freshly exposed bulk, Flood gun is ON, C (1s) BE = 285.0 eV, Ag FWHM = 0.75 eV |
Mg (1s) Spectrum from NIST SRM 614 – Peak-Fit Freshly exposed bulk, Flood gun is ON, C (1s) BE = 285.0 eV, Ag FWHM = 0.75 eV |
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→ Periodic Table | → Six (6) BE Tables |
Ar (2p) Spectrum from NIST SRM 614 – Peak-fit Freshly exposed bulk, Flood gun is ON, C (1s) BE = 285.0 eV, Ag FWHM = 0.75 eV |
Valence Band Signals from NIST SRM 614 – Raw Freshly exposed bulk, Flood gun is ON, C (1s) BE = 285.0 eV, Ag FWHM = 0.75 eV |
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Overlays |
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→ Periodic Table | → Six (6) BE Tables |
Valence Band Spectra – Overlay of SiO2 and NIST SRM 610 | Si (2p) Spectra – Overlay of SiO2 and NIST SRM 610 Freshly exposed bulk, Flood gun is ON, C (1s) BE = 285.0 eV, Ag FWHM = 0.75 eV |
Valence Band Spectra – Overlay of NIST SRM 610 and 612 Freshly exposed bulk, Flood gun is ON, C (1s) BE = 285.0 eV, Ag FWHM = 0.75 eV |
Si (2p) Spectra – Overlay of NIST SRM 610 and 612 Freshly exposed bulk, Flood gun is ON, C (1s) BE = 285.0 eV, Ag FWHM = 0.75 eV |
Overlay of Ar (2p) | Overlay of C (1s) |
Overlay of Valence Band | Overlay of Si (2p) |
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NIST Composition Tables for SRM 614 Preparation and Analysis: Sixty-one trace elements were added to the glass support matrix, which has a nominal composition of 72 % SiO2, 14 % Na2O, 12 % CaO, and 2 % Al2O3 (mass fractions). A list of 29 elements that were added but for which no values have been assigned is provided in Table 4. The material was prepared in rod form and then sliced into wafers. Considerable effort was invested in the manufacturing of the material to ensure sufficient homogeneity to yield a ≤2 % relative repeatability of measurement when an entire wafer is used. Spatial heterogeneity exists within each wafer, which may adversely affect repeatability of microanalysis techniques. Values were assigned using the analytical methods listed in Table 5.
72 % SiO2, 14 % Na2O, 12 % CaO, and 2 % Al2O3 (mass fractions).
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End-of-spectra Price to purchase raw data sets:
Transmission Function Tests |
December 2015 – Transmission Function of Thermo K-Alpha Plus |
→ Periodic Table |
Survey Spectra of Ion Etched Copper (Cr), PEs = 50, 100, 150 and 200 eV |
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→ Periodic Table |
March 2016 – Transmission Function of Thermo K-Alpha Plus |
Survey Spectra of Ion Etched Copper (Cr), PEs = 100, 150 and 200 eV |
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→ Periodic Table |
August 2019 – Transmission Function of Thermo K-Alpha Plus |
Survey Spectra of HOPG (C), PEs = 20, 50, 100 and 200 eV |
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→ Periodic Table |
January 2022 – Transmission Function of Thermo K-Alpha Plus |
Survey Spectra of Ion Etched Copper (Cr), PEs = 100, 120, 140, 160, 180 and 200 eV |