Transmission Function

 



 

Transmission Function

 

 

 

 



 

Transmission Function Correction Equation (D, Shirley) used in SDP v8 Software

 

 

 



 

Comparison of Scofield Cross-sections to Sensitivity Factors used in Multi-Pak Software

Assuming that the Scofield values are correct, then the difference between these SFs is, to a large extent, due to the Transmission Function of the PHI Instrument. 

 

 



 

Inelastic Mean Free Path (IMFP) Values

 

have a direct effect on atom % results (quantitation) and are an integral part of any atom% calculation even though it is often hidden in the software calculation.

 


Photo-Emission Process and Photoelectron Scattering define IMFP values

 

 



Scattering of Photoelectrons Produces Background and Reduces Main Peak Intensities

 

 


 



Graphic Comparison of IMFP values from Pure Metals and Pure Oxides

 

 



 

IMFP-TPP2M Software (produced by S. Tanuma and S. Tougaard)

used to produce IMFPs shown in Periodic Table shown above

NOTE: This FREE software is old, but will run on Windows 10

(Click on Title of Image to download IMFP-TPP2M software in a Zip file.)

 

 



Trendline Establishes/Defines the Exponent used to correct for IMFP

 

The Exponent Factor (i.e. 0.6659) that is used to correct Peak Intensities in Atom % Calculations as a Function of KE of Photoelectrons

Data were Calculated for only Peak BEs from a software produced by S. Tanuma

 

 



 Photoelectron Emission Intensity versus Depth of Origin

(r.f.  IMFP C(1s) = 33 Ang)

 

 



 

 

Transmission Function of Thermo K-Alpha XPS

 

Information in Avantage Software explaining How Transmission Function is measured for K-Alpha XPS system