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XPS Spectra
Zinc (Zn) Compounds
The XPS Spectra section provides raw and processed survey spectra, chemical state spectra, BE values, FWHM values, and overlays of key spectra.
Atom% values from surveys are based on sample, as received, and Scofield cross-sections. Atom% values are corrected for IMFP and PE.
Peak-fits are guides for practical, real-world applications. Peak-fits are not fully optimized or designed to test any theory.

Zinc Fluoride  (ZnF2)
Survey, Peak-fits, BEs, FWHMs, and Peak Labels

→  Periodic Table   → Six (6) BE Tables
Survey Spectrum from ZnF2
Freshly exposed bulk, Flood gun is ON, C (1s) BE = 285.0 eV, Ag (3d5/2) FWHM = 1.3 eV
→  Periodic Table  → Six (6) BE Tables
Zn (2p3/2) Spectrum from ZnF2 – Raw
Fresh exposed bulk, Flood gun is ON, C (1s) BE = 285.0 eV, Ag FWHM = 0.75 eV		 Zn (2p3/2) Spectrum from ZnF2 – Peak-Fit
Freshly exposed bulk, Flood gun is ON, C (1s) BE = 285.0 eV, Ag FWHM = 0.75 eV

 
 
Zn (2p) Spectrum from ZnF2  – Extended Range
Fresh exposed bulk, Flood gun is ON, C (1s) BE = 285.0 eV, Ag FWHM = 0.75 eV		 Zn (2p) Spectrum from ZnF2 – Raw – Vertically Expanded
Freshly exposed bulk, Flood gun is ON, C (1s) BE = 285.0 eV, Ag FWHM = 0.75 eV

→  Periodic Table  → Six (6) BE Tables
F (1s) Spectrum from ZnF2 – Raw
Freshly exposed bulk, Flood gun is ON, C (1s) BE = 285.0 eV, Ag FWHM = 0.75 eV		 F (1s) Spectrum from ZnF2 – Peak-fit
Freshly exposed bulk, Flood gun is ON, C (1s) BE = 285.0 eV, Ag FWHM = 0.75 eV
→  Periodic Table  → Six (6) BE Tables
F (1s) Spectrum from ZnF2 – Raw – Extended Range
Freshly exposed bulk, Flood gun is ON, C (1s) BE = 285.0 eV, Ag FWHM = 0.75 eV		 F (1s) Spectrum from ZnF2 – Raw – Vertically Expanded
Freshly exposed bulk, Flood gun is ON, C (1s) BE = 285.0 eV, Ag FWHM = 0.75 eV
 
→  Periodic Table  → Six (6) BE Tables
C (1s) Spectrum from ZnF2 – Peak-fit – As measured 
Freshly exposed bulk, Flood gun is ON, C (1s) BE = 284.55 eV, Ag FWHM = 0.75 eV		 C (1s) Spectrum from ZnF2 – Peak-Fit – Corrected
Freshly exposed bulk, Flood gun is ON, C (1s) BE = 285.0 eV, Ag FWHM = 0.75 eV
→  Periodic Table  → Six (6) BE Tables
Zn (3s) Spectrum from ZnF2 – Raw
Freshly exposed bulk, Flood gun is ON, C (1s) BE = 285.0 eV, Ag FWHM = 0.75 eV		 Zn (3s) Spectrum from ZnF2 – Peak-Fit
Freshly exposed bulk, Flood gun is ON, C (1s) BE = 285.0 eV, Ag FWHM = 0.75 eV
→  Periodic Table  → Six (6) BE Tables
Zn (3p) Spectrum from ZnF2 – Raw
Freshly exposed bulk, Flood gun is ON, C (1s) BE = 285.0 eV, Ag FWHM = 0.75 eV		 Zn (3p) Spectrum from ZnF2 – Peak-Fit
Freshly exposed bulk, Flood gun is ON, C (1s) BE = 285.0 eV, Ag FWHM = 0.75 eV
→  Periodic Table  → Six (6) BE Tables
  Zn (KLL) Auger Spectrum from ZnF2 – Raw
Freshly exposed bulk, Flood gun is ON, C (1s) BE = 285.0 eV, Ag FWHM = 0.75 eV		 Valence Band Signals from ZnF2 – Raw
Freshly exposed bulk, Flood gun is ON, C (1s) BE = 285.0 eV, Ag FWHM = 0.75 eV
 
Overlays
→  Periodic Table  → Six (6) BE Tables
Valence Band Spectra – Overlay of Zno and ZnF2
Freshly exposed bulk, Flood gun is ON, C (1s) BE = 285.0 eV, Ag FWHM = 0.75 eV		 Zn (2p3/2) Spectra – Overlay of Zno and ZnF2
Freshly exposed bulk, Flood gun is ON, C (1s) BE = 285.0 eV, Ag FWHM = 0.75 eV
→  Periodic Table  → Six (6) BE Tables
Zn (2p3/2) Spectra – Overlay of Zn(SO4) and ZnF2
Freshly exposed bulk, Flood gun is ON, C (1s) BE = 285.0 eV, Ag FWHM = 0.75 eV		 Zn Spectra – Overlay of Zno plasmons and ZnF2 E losses
Freshly exposed bulk, Flood gun is ON, C (1s) BE = 285.0 eV, Ag FWHM = 0.75 eV

End-of-spectra

Price to purchase raw data sets:
Raw spectra – VAMAS ASCII format ($6)
Raw spectra – SDP binary format ($5)
SDP v9 – $145 (3 yr license)

 

 

 

Transmission Function Tests
 

December 2015 – Transmission Function of Thermo K-Znpha Plus
→  Periodic Table 
Survey Spectra of Ion Etched Copper (Cr), PEs = 50, 100, 150 and 200 eV
→  Periodic Table 
March 2016 – Transmission Function of Thermo K-Znpha Plus 
 
Survey Spectra of Ion Etched Copper (Cr), PEs = 100, 150 and 200 eV
→  Periodic Table  
August 2019 – Transmission Function of Thermo K-Znpha Plus
 
Survey Spectra of HOPG (C), PEs = 20, 50, 100 and 200 eV
→  Periodic Table  
January 2022 – Transmission Function of Thermo K-Znpha Plus
Survey Spectra of Ion Etched Copper (Cr), PEs = 100, 120, 140, 160, 180 and 200 eV

 

Six (6) Chemical State Tables of Zn (2p) BEs

 

  • The XPS Library Spectra-Base
  • PHI Handbook
  • Thermo-Scientific Website
  • XPSfitting Website
  • Techdb Website
  • NIST Website

→  Periodic Table 

 

 

Notes of Caution when using Published BEs and BE Tables from Insulators and Conductors:

  • Accuracy of Published BEs
    • The accuracy depends on the calibration BEs used to calibrate the energy scale of the instrument.  Cu (2p3/2) BE can vary from 932.2 to 932.8 eV for old publications
    • Different authors use different BEs for the C (1s) BE of the hydrocarbons found in adventitious carbon that appears on all materials and samples.  From 284.2 to 285.3 eV
    • The accuracy depends on when the authors last checked or adjusted their energy scale to produce the expected calibration BEs
  • There are uncertainties and error ranges in nearly all BEs 
    • Flood guns
  • Worldwide Differences in Energy Scale Calibrations
    • For various reasons authors still use older energy scale calibrations
    • Some authors still adjust their energy scale so Cu (2p3/2) appears at 932.2 eV or 932.8 eV because this is what the maker taught them
    • This range causes BEs in the higher BE end to be larger than expected
    • This variation increases significantly above 600 eV BE
  • Charge Compensation
    • Samples that behave as true insulators normally require the use of a charge neutralizer (electron flood gun with or without Ar+ ions) so that the measured chemical state spectra can be produced without peak-shape distortions or sloping tails on the low BE side of the peak envelop.
    • Floating all samples (conductive, semi-conductive, and non-conductive) and always using the electron flood gun is considered to produce more reliable BEs and is recommended.
  • Charge Referencing Methods for Insulators
    • Charge referencing is a common method, but it can produce results that are less reliable.
    • When an electron flood gun is used, the BE scale will usually shift to lower BE values by 0.01 to 5.0 eV depending on your voltage setting. Normally, to correct for this flood gun induced shift, the BE of the hydrocarbon C (1s) peak maximum from adventitious carbon is used to correct for the charge induced shift.
    • The hydrocarbon peak is normally the largest peak at the lowest BE.
    • Depending on your preference or training, the C (1s) BE assigned to this hydrocarbon peak varies from 284.8 to 285.0 eV.  Other BEs can be as low as 284.2 eV or as high as 285.3 eV
    • Native oxides that still show the pure metal can suffer differential charging that causes the C (1s) and the O (1s) and the Metal Oxide BE to be larger
    • When using the electron flood gun, the instrument operator should adjust the voltage and the XY position of the electron flood gun to produce peaks from a strong XPS signal (eg O (1s) or C (1s) having the most narrow FWHM and the lowest experimentally measured BE.

→  Periodic Table 

Table #1

Zn (2p) Chemical State BEs from:  “The XPS Library Spectra-Base”

C (1s) BE = 285.0 eV for TXL BEs
and C (1s) BE = 284.8 eV for NIST BEs

Element Atomic # Compound As-Measured by TXL or NIST Average BE Largest BE Hydrocarbon C (1s) BE  Source
Zn 30 ZnP2 (N*1) 1020.9 eV 284.8 eV Avg BE – NIST
Zn 30 ZnO (N*10) 1021.4 eV 1022.3 eV 284.8 eV Avg BE – NIST
Zn 30 Zn-O 1021.6 eV 285.0 eV The XPS Library
Zn 30 Zn-S (N*5) 1021.7 eV 1022.0 eV 284.8 eV Avg BE – NIST
Zn 30 Zn – element 1021.8 eV 285.0 eV The XPS Library
Zn 30 ZnSe (N*1) 1021.8 eV 284.8 eV Avg BE – NIST
Zn 30 Zn-Cl2 (N*1) 1021.9 eV 284.8 eV Avg BE – NIST
Zn 30 Zn-Se 1021.9 eV 285.0 eV The XPS Library
Zn 30 Zn-F2 (N*2) 1022.2 eV 1022.8 eV 284.8 eV Avg BE – NIST
Zn 30 ZnS 1022.3 eV 285.0 The XPS Library
Zn 30 Zn-CO3 (N*1) 1022.5 eV 284.8 eV Avg BE – NIST
Zn 30 Zn-CO3 1022.4 eV 285.0 eV The XPS Library
Zn 30 Zn-(OH)2  (N*1) 1022.7 eV) 284.8 eV Avg BE – NIST
Zn 30 ZnI2 (N*2) 1022.9 eV 1023.1 eV 284.8 eV Avg BE – NIST
Zn 30 ZnSO4 (N*2) 1023.0 eV 284.8 eV Avg BE – NIST
Zn 30 ZnSO4 1023.5 eV 285.0 eV The XPS Library

Charge Referencing

  • (N*number) identifies the number of NIST BEs that were averaged to produce the BE in the middle column.
  • Binding Energy Scale Calibration expects Cu (2p3/2) BE = 932.62 eV and Au (4f7/2) BE = 83.98 eV.  BE (eV) Uncertainty Range:  +/- 0.2 eV
  • Charge Referencing of insulators is defined such that the Adventitious Hydrocarbon C (SO) BE (eV) = 285.0 eV.  NIST uses C (1s) BE = 284.8 eV 
  • Note:   Ion etching removes adventitious carbon, implants Ar (+), changes conductivity of surface, and degrades chemistry of various chemical states.
  • Note:  Ion Etching changes BE of C (1s) hydrocarbon peak.
  • TXL – abbreviation for: “The XPS Library” (https://xpslibrary.com).  NIST:  National Institute for Science and Technology (in USA)

 →  Periodic Table 

Table #2

Zn (2p) Chemical State BEs from:  “PHI Handbook”

C (1s) BE = 284.8 eV

Copyright ©:  Ulvac-PHI

Table #3

Zn (2p) Chemical State BEs from:  “Thermo-Scientific” Website

C (1s) BE = 284.8 eV

Chemical state Binding energy (eV), Zn (2p3/2)
Zn metal 1021.7
ZnO ~1022

→  Periodic Table 

Copyright ©:  Thermo Scientific website

Table #4

Zn (2p) Chemical State BEs from:  “XPSfitting” Website

Chemical State BE Table derived by Averaging BEs in the NIST XPS database of BEs
C (1s) BE = 284.8 eV

Copyright ©:  Mark Beisinger

Table #5

Zn (2p) Chemical State BEs from:  “Techdb.podzone.net” Website

XPS Spectra – Chemical Shift | Binding Energy
C (1s) BE = 284.6 eV

Element Level Compound B.E.(eV) min max
Zn 2p3/2 Phosphide 1020.7 ±0.2 1020.5 ～ 1020.9
Zn 2p3/2 (Me4N)2ZnBr4 1021.0 ±0.3 1020.7 ～ 1021.2
Zn 2p3/2 Zn(acac)2 1021.5 ±0.3 1021.2 ～ 1021.7
Zn 2p3/2 ZnRh2O4 1021.8 ±0.3 1021.5 ～ 1022.0
Zn 2p3/2 Zn 1021.9 ±0.1 1021.8 ～ 1021.9
Zn 2p3/2 Zn4Si2O7(OH)2･2H2O 1022.0 ±0.3 1021.7 ～ 1022.3
Zn 2p3/2 ZnCr2O4 1022.1 ±0.3 1021.8 ～ 1022.3
Zn 2p3/2 ZnO 1022.1 ±0.4 1021.7 ～ 1022.5
Zn 2p3/2 ZnS 1022.5 ±0.2 1022.3 ～ 1022.7
Zn 2p3/2 Halides 1022.6 ±0.4 1022.2 ～ 1023.0
Zn 2p3/2 ZnSO4 1023.1 ±0.3 1022.8 ～ 1023.3

Histograms of NIST BEs from Zn (2p)
NIST Database defines Adventitious Hydrocarbon C (1s) BE = 284.8 eV for all insulators.

Histogram indicates Zn (2p) BE = 1022.0 eV for Zinc Metal (Zn)
based on 15 literature BEs		 Histogram indicates Zn (2p) BE = 1022.0 eV for Zinc Oxide
 based on 12 literature BEs

Table #6

NIST Database of Zn (2p) Binding Energies

NIST Standard Reference Database 20, Version 4.1

Data compiled and evaluated
by
Znexander V. Naumkin, Anna Kraut-Vass, Stephen W. Gaarenstroom, and Cedric J. Powell
©2012 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. Znl rights reserved.